Synthesis of side-chain functionalized polynorbornene supported half-metallocene catalysts and their application in ethylene polymerization

• Thakur Ashutosh

  北陸先端科学技術大学院大学マテリアルサイエンス研究科

• 寺野 稔

  北陸先端科学技術大学院大学マテリアルサイエンス研究科

• 谷池 俊明

  北陸先端科学技術大学院大学マテリアルサイエンス研究科

抄録

The purpose of this research is to design a new class of olefin polymerization catalysts using soluble polynorbornene (PNB) chain as the carrier. For the said design, we have adopted two strategies: (i) Firstly, side chain functionalised soluble polymer supports have been synthesized via Grubbs catalysed ring opening metathesis polymerization (ROMP). The resultant polymers have been used to support half-metallocene catalysts. (ii) Secondly, we have synthesized norbornene derivative containing aryloxide pendant group, which is coordinated to half-metallocene catalyst. The metal containing norbornene derivative has been copolymerized with norbornene via Grubbs catalysed ROMP in order to fulfil the catalyst design. The synthesized catalysts have been employed in ethylene polymerization.

収録刊行物

• 石油学会 年会・秋季大会講演要旨集

  石油学会 年会・秋季大会講演要旨集 2016f (0), 151-, 2016

  公益社団法人 石油学会

詳細情報

• CRID: 1390001205586941440
• NII論文ID: 130005295632
• DOI: 10.11523/sekiyu.2016f.0_151
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可