Crystal Structure of (2-Picolinato)bis(2,2′-bipyridine)ruthenium(II) Chloride

• TOYAMA Mari

  Department of Chemistry of Functional Molecules, Faculty of Science and Engineering, Konan University

• NAKAYASU Toshifumi

  Department of Chemistry of Functional Molecules, Faculty of Science and Engineering, Konan University

• NAGAO Noriharu

  Department of Applied Chemistry, School of Science and Technology, Meiji University

抄録

The crystal structure of the title complex, [Ru(pic)(bpy)₂]Cl·CH₃CN·1.5H₂O (pic = 2-picolinato; bpy = 2,2′-bipyridine), was determined by X-ray crystallography. Single crystals were obtained by the vapor diffusion of diethyl ether into an acetonitrile solution of [Ru(pic)(bpy)₂]Cl. The complex crystallized in a monoclinic system, and was characterized as: I2/a, a = 15.40850(14), b = 13.07370(14), c = 27.3830(3)Å, β = 98.0922(9)°, Z = 8, V = 5461.27(10)ų. The R1 and wR2 values were 0.0267 and 0.0714, respectively, for 5008 reflections.

収録刊行物

• X-ray Structure Analysis Online

  X-ray Structure Analysis Online 33 (0), 11-13, 2017

  社団法人 日本分析化学会

キーワード

• Materials Chemistry
• Analytical Chemistry

詳細情報

• CRID: 1390001205300249344
• NII論文ID: 130005439690
• DOI: 10.2116/xraystruct.33.11
• ISSN: 18833578
• Web Site: https://www.jstage.jst.go.jp/article/xraystruct/33/0/33_11/_pdf
• 本文言語コード: en
• データソース種別:
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