Determination of Eleven Organophosphorus Pesticide Residues in Textiles by Using HPLC-HRMS

• HU Ting-Ting

  School of Public Health, Jilin University Department of Technical Center, Jilin Entry Exit Inspection and Quarantine Bureau

• LU Chun-Mei

  Department of Technical Center, Jilin Entry Exit Inspection and Quarantine Bureau

• LI Han

  School of Public Health, Jilin University Department of Nosocomial Infection Management, The First Hospital of Jilin University

• ZHANG Zai-Xiao

  College of Life Sciences, Jilin University

• ZHAO Yun-Hui

  Department of Technical Center, Jilin Entry Exit Inspection and Quarantine Bureau

• LI Juan

  School of Public Health, Jilin University

抄録

The overuse of organophosphorus pesticides on cotton production is a big concern in China today. Therefore, developing methods for the rapid screening and confirming of pesticide residues in textiles has become a top public health security priority. Here, a method was established for the rapid screening and quantifying of 11 kinds of organophosphorus pesticides (ethoprophos, coumaphos, profenofos, diazinon, ethion, parathion, phosalone, quinalphos, dicrotophos, azinphos methyl, and tribuphos) in textiles by high-performance liquid chromatography high-resolution mass spectrometry (HPLC-HRMS). Rapid screening and quantifying could be completed by using software of Peakview and MultiQuant. Samples were extracted by the method of modified QuEChERS (Quick, Easy, Cheap, Effective, Rugged and Safe) and analyzed in the positive mode with MS detection. The results showed that the limits of detection were between 0.1 and 5.0 ng g⁻¹, with correlation coefficients above 0.9990. The recoveries were in the range of 70.3 – 109.8%, with relative standard deviations from 5.1 to 16.4%. This method is accurate and simple, which can be used in the rapid screening and quantitative analysis of 11 kinds of organophosphorus pesticides in textiles.

収録刊行物

• Analytical Sciences

  Analytical Sciences 33 (9), 1027-1032, 2017

  社団法人 日本分析化学会

キーワード

• Textiles
• organophosphoruspesticide
• high-performance liquid chromatography high-resolution mass spectrometry
• rapid screening

詳細情報

• CRID: 1390282679236078336
• NII論文ID: 130006071170
• NII書誌ID: AA10500785
• DOI: 10.2116/analsci.33.1027
• ISSN: 13482246
• ISSN: 09106340
• NDL書誌ID: 028509017
• PubMed: 28890486
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I028509017
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.33.1027.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.33.1027/fulltext.html
• Web Site: https://www.jstage.jst.go.jp/article/analsci/33/9/33_1027/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • PubMed
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可