Photoreversible Interference Color Modulation to Multicolor in Photochromic Molecular Crystals
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- Kohei Morimoto
- Department of Applied Chemistry, Graduate School of Engineering, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585 , Japan
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- Hajime Tsujioka
- Department of Applied Chemistry, Graduate School of Engineering, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585 , Japan
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- Daichi Kitagawa
- Department of Applied Chemistry, Graduate School of Engineering, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585 , Japan
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- Seiya Kobatake
- Department of Applied Chemistry, Graduate School of Engineering, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585 , Japan
抄録
<jats:title>Abstract</jats:title> <jats:p>Functional molecular crystals responsive to external stimuli represent a new frontier for material chemistry and crystal engineering. Here, we report on the photoreversible interference color change in single crystals composed of a photochromic diarylethene derivative, 1,2-bis(2-ethyl-5-phenyl-3-thienyl)perfluorocyclopentene (1a). When crystal 1a was observed by rotating the sample stage at 45° from the extinction position under crossed Nicols, it showed an interference color. Upon irradiation with ultraviolet (UV) light, the interference color changed dramatically and instantaneously in response to photoirradiation due to the photocyclization reaction from the open-ring form to the closed-ring form. The change was quite sensitive to the photochromic reaction. It is attributable to the large decrease in retardation induced by the photocyclization reaction in crystals. These results might provide new opportunities for application of photochromic crystals.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 92 (8), 1299-1304, 2019-06-04
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360002219097136896
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- NII論文ID
- 130007690045
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- ISSN
- 13480634
- 00092673
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- データソース種別
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