Nickel-catalyzed [4 + 2] Cycloaddition of Styrenes with Arynes via 1:1 Cross-coupling : Synthesis of 9,10-Dihydrophenanthrenes

• 藤田, 健志

• 市川, 淳士

• Kubo, Teruhiko

抄録

The [4 + 2] cycloaddition of styrenes with arynes was achieved via 1:1 cross-coupling by a nickel catalyst. This protocol applies to a variety of styrenes and arynes generated in situ from o-(trimethylsilyl)aryl triflates to afford 9,10-dihydrophenanthrenes involving substituted aromatic rings. By using this method, a naturally occurring stilbenoid is easily synthesized.

収録刊行物

• Chemistry Letters

  Chemistry Letters 49 (3), 264-266, 2020-03

  Chemical Society of Japan

キーワード

• General Chemistry

詳細情報

• CRID: 1050003824951251328
• NII論文ID: 130007805927
• NII書誌ID: AA00603318
• ISSN: 03667022
• ISSN: 13480715
• DOI: 10.1246/cl.190906
• HANDLE: 2241/00160261
• Web Site: https://tsukuba.repo.nii.ac.jp/records/54853
• Web Site: http://www.journal.csj.jp/doi/pdf/10.1246/cl.190906
• 本文言語コード: en
• 資料種別: journal article
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