A Hole Theory of Polymer Liquids and Glasses. I. Partition Function and Equation of State for Polymer Liquids

• Nose Takuhei

  Department of Polymer Technology, Tokyo Institute of Technology

抄録

The hole theory of simple liquids is applied to polymer liquids and their partition function is derived by application of the method first proposed by Prigogine et al. The equation of state derived does not satisfy the principle of corresponding states. As for the volume dependence of internal pressure at atomspheric pressure, the model where the cell volume is constant gives closer agreement with observed results than the more general model in which the cell volume and the number of holes are both allowed to vary. The molecular parameters needed to check the theory are determined for various polymers.

収録刊行物

• Polymer Journal

  Polymer Journal 2 (2), 124-133, 1970

  The Society of Polymer Science, Japan

キーワード

• Hole Theory
• Polymer Liquids
• Equation of State
• Corresponding States
• Internal Pressure

詳細情報

• CRID: 1390282681268209152
• NII論文ID: 30001925631
• NII論文ID: 130004767950
• DOI: 10.1295/polymj.2.124
• ISSN: 13490540
• ISSN: 00323896
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可