Solvent effects in radical copolymerization. I. Acrylamide

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<jats:title>Abstract</jats:title><jats:p>Acrylamide has been free radical copolymerized with styrene and methyl methacrylate at 70°C in different solvents (dioxane, dioxane/ethanol mixture, ethanol). A strong influence of the solvent on the copolymer compositions has been observed; particularly copolymers richer in acrylamide have always been obtained in dioxane.</jats:p><jats:p>These results indicate that the nature of the solvent (polarity, dielectric constant <jats:italic>etc</jats:italic>.) could affect the polarity and the reactivity of the acrylamide double bond as well as the stability of the growing radical. Other factors are also discussed.</jats:p>

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