Radically initiated polymerization of a methacryloylamido‐terminated saccharide, 2. Copolymerization with 2‐hydroxyethyl methacrylate

• Bérangère Badey

• Paul Boullanger

• Alain Domard

• Philippe Cros

• Thierry Delair

• Christian Pichot

抄録

Kinetics of radically initiated copolymerization of 6‐deoxy‐6‐methacryloylamido‐ D ‐glucopyranose (MAG) with 2‐hydroxyethyl methacrylate (HEMA) was investigated at 60°C in water using 4,4′‐azobis(4‐cyanopentanoic acid) as initiator. Reactivity ratios of the binary system were determined to be r HEMA = 3.50 and r MAG = 0.60, indicating a strong copolymerization drift as polymerization proceeds. Copolymers with homogeneous composition were prepared using a simple and easy method based on the knowledge of the consumption rate of each monomer. These copolymers were then characterized with regard to composition (by 1 H NMR) and physicochemical properties in aqueous media (using SEC with MALLS and refractometry detection and viscosimetric measurements).

収録刊行物

• Macromolecular Chemistry and Physics

  Macromolecular Chemistry and Physics 198 (4), 945-957, 1997-04

  Wiley

キーワード

• Materials Chemistry
• Organic Chemistry
• Polymers and Plastics
• Physical and Theoretical Chemistry
• Condensed Matter Physics

詳細情報

• CRID: 1360018297893631872
• NII論文ID: 30008288367
• DOI: 10.1002/macp.1997.021980403
• ISSN: 15213935
• ISSN: 10221352
• Web Site: https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fmacp.1997.021980403
• Web Site: https://onlinelibrary.wiley.com/doi/pdf/10.1002/macp.1997.021980403
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