The noncoincidence effect in the ν3 band of liquid methyl fluoride

• Taehyoung Zyung

  Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, Texas, 79409

• Richard E. Wilde

  Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, Texas, 79409

抄録

The 11 cm−1 splitting observed in the ν3 region of the Raman spectrum of liquid methyl fluoride is explained as arising from the noncoincidence effect. An interpretation of the solid-state infrared and Raman spectra is based upon correlation-field splitting effects. An analysis of these two effects suggests that the transition-dipole moment increases from 1.31×10−6 C kg−1/2 in the gaseous state to 2.28×10−6 C kg−1/2 in the solid state.

収録刊行物

• The Journal of Chemical Physics

  The Journal of Chemical Physics 86 (11), 5940-5944, 1987-06-01

  AIP Publishing

キーワード

• Physical and Theoretical Chemistry
• General Physics and Astronomy

詳細情報

• CRID: 1360862723065804544
• NII論文ID: 30015656351
• DOI: 10.1063/1.452478
• ISSN: 10897690
• ISSN: 00219606
• Web Site: https://pubs.aip.org/aip/jcp/article-pdf/86/11/5940/18964579/5940_1_online.pdf
• データソース種別:
  • Crossref
  • CiNii Articles