Liquid polymer conformation on solid surfaces

DOI PDF 被引用文献7件
  • V. J. Novotny
    IBM Research Division, Almaden Research Center, San Jose, California 95120-6099
  • I. Hussla
    IBM Research Division, Almaden Research Center, San Jose, California 95120-6099
  • J.-M. Turlet
    IBM Research Division, Almaden Research Center, San Jose, California 95120-6099
  • M. R. Philpott
    IBM Research Division, Almaden Research Center, San Jose, California 95120-6099

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<jats:p>Infrared spectra of thin films of polyperfluoroethers on metal and silicon dioxide surfaces were obtained for films with thicknesses between 1 and 1000 nm by p-polarized reflection and modulated polarization techniques. Changes in frequencies and relative intensities of vibrational peaks with film thickness suggest that the conformation of liquid polymers on surfaces is unlike bulk conformation, with polymer chains extended preferentially along the surface.</jats:p>

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