Competition between atomic and molecular chlorine elimination in the infrared multiphoton dissociation of CF2Cl2
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- D. Krajnovich
- Materials and Molecular Research Division, Lawrence Berkeley Laboratory, University of California, Berkeley, California 94720
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- F. Huisken
- Materials and Molecular Research Division, Lawrence Berkeley Laboratory, University of California, Berkeley, California 94720
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- Z. Zhang
- Materials and Molecular Research Division, Lawrence Berkeley Laboratory, University of California, Berkeley, California 94720
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- Y. R. Shen
- Materials and Molecular Research Division, Lawrence Berkeley Laboratory, University of California, Berkeley, California 94720
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- Y. T. Lee
- Materials and Molecular Research Division, Lawrence Berkeley Laboratory, University of California, Berkeley, California 94720
抄録
<jats:p>Infrared multiphoton dissociation of CF2Cl2 has been reinvestigated by the crossed laser-molecular beam technique using a high repetition rate CO2 TEA laser. Both the atomic and molecular chlorine elimination channels were observed: (1) CF2Cl2→CF2Cl+Cl and (2) CF2Cl2→CF2+Cl2. No evidence was found for secondary dissociation of CF2Cl at laser energy fluences up to 8 J/cm2. Center-of-mass product translational energy distributions were obtained for both dissociation channels. In agreement with previous work, the products of reaction (1) are found to have a statistical translational energy distribution. The products of reaction (2) are formed with a mean translational energy of 8 kcal/mol, and the distribution peaks rather sharply about this value, indicating a sizeable exit barrier to molecular elimination. The product branching ratio was directly determined. Reaction (2) accounts for roughly 10% of the total dissociation yield in the fluence range 0.3–8 J/cm2. These results provide an additional test of the statistical theory of unimolecular reactions.</jats:p>
収録刊行物
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- The Journal of Chemical Physics
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The Journal of Chemical Physics 77 (12), 5977-5989, 1982-12-15
AIP Publishing
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詳細情報 詳細情報について
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- CRID
- 1363107370616656384
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- NII論文ID
- 30015678331
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- DOI
- 10.1063/1.443841
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- ISSN
- 10897690
- 00219606
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- データソース種別
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