ESR of the quartet states of randomly oriented molecules: Calculation of the line shape and detection of the zero-field splitting
-
- J. Brickmann
- Institut für Physikalische Chemie, Universität Freiburg, Freiburg/Br., Albertstr. 21, Germany
-
- G. Kothe
- Institut für Physikalische Chemie, Universität Freiburg, Freiburg/Br., Albertstr. 21, Germany
抄録
<jats:p>The ESR spectrum of the quartet states of randomly oriented molecules with axial symmetry is discussed. The absorption curves of the Δm = 1, Δm = 2, and Δm = 3 transitions are calculated in first order perturbation approximation. The line broadening is explicitly taken into account. The experimental spectrum of an alternant hydrocarbon agrees sufficiently well with the theoretical predictions. The shape of the absorption curve permits the ready determination of the zero-field parameters of quartet molecules.</jats:p>
収録刊行物
-
- The Journal of Chemical Physics
-
The Journal of Chemical Physics 59 (6), 2807-2814, 1973-09-15
AIP Publishing
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1360011146039601024
-
- NII論文ID
- 30015703238
-
- ISSN
- 10897690
- 00219606
-
- データソース種別
-
- Crossref
- CiNii Articles