Dielectric Investigations on Nitromethane and Chloropicrin

• C. P. Smyth

  Frick Chemical Laboratory, Princeton University

• W. S. Walls

  Frick Chemical Laboratory, Princeton University

抄録

The dielectric constants and densities of dilute solutions of nitromethane in heptane and of chloropicrin in heptane and in benzene have been measured and used to calculate the dipole moments of the solute molecules. The values thus calculated are considerably lower than those previously obtained in the gaseous state and are not well represented by the empirical equation of Müller. Measurement of the dielectric constant of pure liquid and solid nitromethane fails to show the existence of molecular rotation in the solid state. It is concluded, therefore, that the heavier molecule of chloropicrin does not rotate in the crystal.

収録刊行物

• The Journal of Chemical Physics

  The Journal of Chemical Physics 3 (9), 557-559, 1935-09-01

  AIP Publishing

キーワード

• Physical and Theoretical Chemistry
• General Physics and Astronomy

詳細情報

• CRID: 1360018298313995520
• NII論文ID: 30015708261
• DOI: 10.1063/1.1749728
• ISSN: 10897690
• ISSN: 00219606
• Web Site: https://pubs.aip.org/aip/jcp/article-pdf/3/9/557/18788763/557_1_online.pdf
• データソース種別:
  • Crossref
  • CiNii Articles