Raman Effect, Infra-Red Absorption, Dielectric Constant, and Electron Diffraction in Relation to Internal Rotation

DOI PDF 被引用文献5件
  • San-ichiro Mizushima
    Chemical Laboratory, Faculty of Science, Tokyo Imperial University, Tokyo, Japan
  • Yonezo Morino
    Chemical Laboratory, Faculty of Science, Tokyo Imperial University, Tokyo, Japan
  • Itaru Watanabe
    Chemical Laboratory, Faculty of Science, Tokyo Imperial University, Tokyo, Japan
  • Takehiko Simanouti
    Chemical Laboratory, Faculty of Science, Tokyo Imperial University, Tokyo, Japan
  • Shigeto Yamaguchi
    Chemical Laboratory, Faculty of Science, Tokyo Imperial University, Tokyo, Japan

抄録

<jats:p>The relative intensities of Raman lines of 1,2-dichloroethane were determined in the gaseous state as well as in the liquid state. The result combined with that of the dipole measurement in the gaseous state enabled us to determine the equilibrium isomeric ratio of the trans- and the gauche molecules, which was in good agreement with that obtained from the absorption measurement of infra-red spectra. This ratio could also explain satisfactorily the result of an electron diffraction experiment made by us for the vapor of 1,2-dichloroethane. The statistical entropy of dihalogenoethanes was calculated from the molecular data and was compared with the third law entropy obtained from the thermal measurement. The frequencies of torsional oscillation about the C–C bond as axis were determined by the difference method and were found to be in agreement with the lowest frequencies of the observed Raman spectra.</jats:p>

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