Mechanisms of silicon nitride etching by electron cyclotron resonance plasmas using SF6- and NF3-based gas mixtures

  • C. Reyes-Betanzo
    Instituto Nacional de Astrofı́sica, Óptica y Electrónica—INAOE, Apartado Postal 51, CP 72000, Puebla, Pue. México
  • S. A. Moshkalyov
    Centro de Componentes Semiconductores—CCS, UNICAMP, C.P. 6061, CEP 13083-970, Campinas, SP, Brazil
  • A. C. S. Ramos
    Instituto de Fı́sica “Gleb Wataghin”—IFGW, UNICAMP, CEP 13083-970, Campinas, SP, Brazil
  • J. W. Swart
    Centro de Componentes Semiconductores—CCS, UNICAMP, C.P. 6061, CEP 13083-970, Campinas, SP, Brazil

抄録

<jats:p>The results of a study of SiNx, SiO2, and Si etching in a high-density electron cyclotron resonance plasma using mixtures containing SF6, NF3, N2, O2, and Ar are presented. Higher selectivities of SiNx etching over SiO2 (up to ∼100) were achieved with NF3, while higher selectivities over Si (up to 5–10) were obtained with SF6-based mixtures. Plasma and surface processes responsible for etching are analyzed, and mechanisms of nitride etching in NF3-based plasmas are proposed.</jats:p>

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