Scroll-Shaped Waves of Chemical Activity in Three Dimensions

  • Arthur T. Winfree
    Department of Biological Sciences, Purdue University, West Lafayette, Indiana 47907

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<jats:p>Ferric ions catalyze the oxidation of malonate by bromate in acid solution, sometimes at a spatially uniform, steady rate, but sometimes in a self-regenerating three-dimensional wave which resembles a rotating scroll, often with its axis closed in a ring. In cross section perpendicular to the axis, one sees an involute spiral emerging from a thin cylindrical core. This "dissipative structure" organizes reaction stages periodically in space and time everywhere except along its rotation axis, which may therefore be a thermodynamically unique locus.</jats:p>

収録刊行物

  • Science

    Science 181 (4103), 937-939, 1973-09-07

    American Association for the Advancement of Science (AAAS)

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