H<sub>2</sub>O<sub>2</sub> Decomposition and Its Impact on Silicon Surface Roughening and Gate Oxide Integrity
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- Schmidt Harald F.
- IMEC, Kapeldreef 75, B–3001 Leuven, Belgium
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- Meuris Marc
- IMEC, Kapeldreef 75, B–3001 Leuven, Belgium
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- Mertens Paul W.
- IMEC, Kapeldreef 75, B–3001 Leuven, Belgium
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- Rotondaro Antonio L. P.
- IMEC, Kapeldreef 75, B–3001 Leuven, Belgium
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- Heyns Marc M.
- IMEC, Kapeldreef 75, B–3001 Leuven, Belgium
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- Hurd Trace Q.
- Texas Instruments, Dallas, TX, U.S.A.
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- Hatcher Zach
- Ashland Chemical, Columbus, OH, U.S.A.
書誌事項
- タイトル別名
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- H2O2 Decomposition and Its Impact on Silicon Surface Roughening and Gate Oxide Integrity.
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抄録
In this study the impact of temperature and metal contamination on the stability of hydrogen peroxide in the two most common wet chemical cleaning mixtures for wafer process operations has been investigated. The stability of the caustic mixture ( NH4OH/H2O2/H2O) was found to be very sensitive to certain metallic contaminations in the sub-ppb range, while the stability of the acid mixture ( HCl/H2O2/H2O) is mainly influenced by non metallic, anionic components of the solution itself. We observed also a strong oscillating behaviour of the rate of the oxygen gas evolution caused by the decomposition of H2O2. Furthermore it was found, that the oxygen gas bubbles, formed by the decomposition of hydrogen peroxide cause a certain kind of micro-roughness on the silicon surface through a micro masking mechanism. In a series of experiments we could prove that this kind of surface roughness has a significant impact on the integrity of thin gate oxides.
収録刊行物
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- Japanese Journal of Applied Physics
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Japanese Journal of Applied Physics 34 (2B), 727-731, 1995
The Japan Society of Applied Physics
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詳細情報 詳細情報について
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- CRID
- 1390282681222141696
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- NII論文ID
- 210000038295
- 110003954797
- 30021821835
- 130004521015
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- NII書誌ID
- AA10457675
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- ISSN
- 13474065
- 00214922
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可