Ionic Conduction and Photoisomerization in Azobenzene Langmuir-Blodgett Films Adsorbing Cyanine Dyes.

• Shinbo Kazunari

  Graduate School of Science and Technology, Niigata University, Ikarashi 2–8050, Niigata 950–21, Japan

• Kontani Tadashi

  Graduate School of Science and Technology, Niigata University, Ikarashi 2–8050, Niigata 950–21, Japan

• Watanabe Mitsuhiro

  Department of Electrical and Electronic Engineering, Niigata University, Ikarashi 2–8050, Niigata 950–21, Japan

• Fukami Tetsuo

  Graduate School of Science and Technology, Niigata University, Ikarashi 2–8050, Niigata 950–21, Japan

• Kato Keizo

  Graduate School of Science and Technology, Niigata University, Ikarashi 2–8050, Niigata 950–21, Japan

• Kaneko Futao

  Department of Electrical and Electronic Engineering, Niigata University, Ikarashi 2–8050, Niigata 950–21, Japan

• Kobayashi Satoshi

  Department of Material Science and Technology, Niigata University, Ikarashi 2–8050, Niigata 950–21, Japan

書誌事項

タイトル別名

• Ionic Conduction and Photoisomerization

抄録

Azobenzene (Az) Langmuir-Blodgett (LB) films adsorbing cyanine dyes (NK-3) were deposited and the electrical properties were investigated in detail. The current vs electric field characteristics suggested ionic hopping conduction, and the transient current properties showed current peaks due to migration of mobile ions. The thermally stimulated currents (TSCs) were also due to the ionic space charge polarization, that is, displacement of mobile ions over long distances in the LB films. These results indicated that the electrical properties of the Az LB devices are strongly dependent on the mobile ions in the devices. In addition, the TSC and the short-circuit photocurrent properties due to the dyes were also changed by isomerization of the Az molecules. The results showed that the ionic space charge polarization and the aggregates of the dyes were affected by the isomerization.

収録刊行物

• Japanese Journal of Applied Physics

  Japanese Journal of Applied Physics 35 (9A), 4765-4769, 1996

  The Japan Society of Applied Physics

キーワード

• adsorption Langmuir-Blodgett method
• azobenzene
• photoisomerization
• cyanine dye
• ionic conduction
• thermally stimulated current

詳細情報

• CRID: 1390282681226492416
• NII論文ID: 10004613393
• NII論文ID: 30021825170
• NII論文ID: 130004522821
• NII論文ID: 210000039690
• NII書誌ID: AA10457675
• DOI: 10.1143/jjap.35.4765
• ISSN: 13474065
• ISSN: 00214922
• NDL書誌ID: 4060164
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4060164
• Web Site: https://iopscience.iop.org/article/10.1143/JJAP.35.4765
• Web Site: https://iopscience.iop.org/article/10.1143/JJAP.35.4765/pdf
• 本文言語コード: en
• データソース種別:
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