Band-Gap Energy Anomaly and Sublattice Ordering in GaInP and AlGaInP Grown by Metalorganic Vapor Phase Epitaxy

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<jats:p> The previously reported photoluminescence(PL)-peak-energy anomaly problem for Ga<jats:sub>0.5</jats:sub>In<jats:sub>0.5</jats:sub>P grown on GaAs by metalorganic vapor phase epitaxy (MOVPE) was studied in detail. X-ray microprobe analysis, and optical transmission spectra measurements were carried out to examine alloy compositions and band-gap energies (<jats:italic>E</jats:italic> <jats:sub>g</jats:sub>s), respectively. The MOVPE growth condition dependence of {1/2, 1/2, 1/2} superlattices (SLs) on the cation sublattice in Ga<jats:sub>0.5</jats:sub>In<jats:sub>0.5</jats:sub>P was studied in detail, using transmission electron microscopy. The correlation between the <jats:italic>E</jats:italic> <jats:sub>g</jats:sub> anomaly and the SLs was examined in detail and established. Raman spectra seemed to show zone-folding effects due to the monolayer SL. A similar <jats:italic>E</jats:italic> <jats:sub>g</jats:sub> anomaly was reported for AlGaInP. AlGaInP and AlInP were also found to show the same SLs. </jats:p>

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