2‐Alkylcyclobutanones from the radiolysis of triglycerides

DOI Web Site 被引用文献5件
  • P. R. Letellier
    Department of Food Science and Technology University of Massachusetts Amherst Massachusetts 01002
  • W. W. Nawar
    Department of Food Science and Technology University of Massachusetts Amherst Massachusetts 01002

抄録

<jats:title>Abstract</jats:title><jats:p>A cyclic compound was isolated from the radiolytic products of each of the simple triglycerides containing C<jats:sub>6</jats:sub>, C<jats:sub>8</jats:sub>, C<jats:sub>10</jats:sub>, C<jats:sub>12</jats:sub>, C<jats:sub>14</jats:sub>, C<jats:sub>16</jats:sub> and C<jats:sub>18</jats:sub> fatty acids. In each case the compound was identified as the 2‐alkylcyclobutanone of the same carbon number as the precursor fatty acid. A mechanism is proposed for the production of these compounds which involves the formation of a six‐membered ring intermediate, cyclization and cleavage at the acyl‐oxy bond.</jats:p>

収録刊行物

  • Lipids

    Lipids 7 (1), 75-76, 1972-01

    Wiley

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