Determination and Speciation of Aluminum in Soil Extracts by High-Performance Liquid Chromatography with Fluorescence Detection Using 5-Sulfo-8-quinolinol.

• TSUNODA Kin-ichi

  Department of Chemistry, Gunma University

• YAGASAKI Toshiyuki

  Department of Chemistry, Gunma University

• AIZAWA Shoichi

  Department of Chemistry, Gunma University

• AKAIWA Hideo

  Department of Chemistry, Gunma University

• SATAKE Ken-ichi

  National Institute for Environmental Studies

書誌事項

タイトル別名

• Determination and Speciation of Aluminu

抄録

Cation exchange and size exclusion high-performance liquid-chromatographic methods with postcolumn fluorescence detection using 5-sulfo-8-quinolinol were applied to the chemical speciation of aluminum in soil-extract samples. The addition of an appropriate amount of F^- to the postcolumn reagent solution makes it possible to eliminate the interference of F^- in a sample with Al³⁺ detection. The reliability of this method was evaluated by a computer-assisted equilibrium calculation for aluminum species and ICP atomic emission spectrometry. Considerable parts of water-soluble Al³⁺ (the Al³⁺ fraction extracted into distilled water) in both sedimentary and granitoid soil samples were found to be complexed with organic substances. On the other hand, exchangeable Al³⁺ (the Al³⁺ fraction extracted into 1mol dm^-3 KCl) in granitoid soil samples was mostly free Al³⁺

収録刊行物

• Analytical Sciences

  Analytical Sciences 13 (5), 757-764, 1997

  社団法人 日本分析化学会

キーワード

• Aluminum
• soil extract
• high-performance liquid chromatography
• 5-sulfo-8-quinolinol

詳細情報

• CRID: 1390001204252210688
• NII論文ID: 130003528217
• NII論文ID: 30031575012
• NII論文ID: 10002412803
• NII書誌ID: AA10500785
• DOI: 10.2116/analsci.13.757
• COI: 1:CAS:528:DyaK2sXmslShtrs%3D
• ISSN: 13482246
• ISSN: 09106340
• NDL書誌ID: 4317192
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4317192
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.13.757.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.13.757/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci1985/13/5/13_5_757/_pdf
• 本文言語コード: en
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