推定熱化学的関数値によるヒドロキシ安息香酸類のカルボキシル化反応の考察

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  • Studies on Carboxylation of Hydroxybenzoic Acids in Terms of Estimated Thermochemical Data
  • 推定熱化学的関数値によるヒドロキシ安息香酸類のカルボキシン化反応の考察(ノート)
  • スイテイ ネツカガクテキ カンスウチ ニヨル ヒドロキシ アンソクコウサンルイ

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Recently, by means of microthermal analysis, 4-hydroxyisophthalic acid was found to be formed as an intermediate in both carboxylation of alkali phenolates and rearrangement of alkali salicylates into alkali p-hydroxybenzoates. The thermodynamic studies based on th e argument for the chemical equilibrium suggested in the previous paper were made by using the thermochemical data estimated from the additive nature of the component data.<BR>It was found that many experimental facts were interpreted well in terms of the results obtained by these studies.

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