Low temperature synthesis of 12CaO・7Al₂O₃ from calcium sulfite waste
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- TAKEI Takahiro
- Center for Crystal Science and Technology, University of Yamanashi
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- NAKAMURA Maho
- Center for Crystal Science and Technology, University of Yamanashi
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- MIURA Akira
- Center for Crystal Science and Technology, University of Yamanashi
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- KUMADA Nobuhiro
- Center for Crystal Science and Technology, University of Yamanashi
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- OGIHARA Kiyohiko
- Ogihara INC., Ltd
書誌事項
- タイトル別名
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- Low temperature synthesis of 12CaO·7Al<sub>2</sub>O<sub>3</sub> from calcium sulfite waste
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抄録
One of the calcium aluminate, 12CaO·7Al2O3, was synthesized from calcium sulfite hemihydrate waste which was produced as a by-product of calcium polysulfide. The calcium sulfite waste was at first pre-treated by sodium salts, Na2CO3 and Na2C2O4. Then, the waste was converted to the CaCO3 and CaC2O4, respectively. From these pre-treated sample, 12CaO·7Al2O3 phase was formed at 850°C for the converted CaCO3 from Na2CO3 and at 650°C for the converted CaC2O4 from Na2C2O4. These crystallization temperatures are much lower than from reagent CaCO3 and CaC2O4 at 1250 and 850°C, respectively. The reason of such reduction of crystallized temperature may result from impurity Fe2O3 including in the by-product. Actually, addition of Fe2O3 into the reagent CaCO3 posed decrease of crystallization temperature of 12CaO·7Al2O3 from 1250 to 1050°C.
収録刊行物
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- Journal of the Ceramic Society of Japan
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Journal of the Ceramic Society of Japan 121 (1409), 31-35, 2013
公益社団法人 日本セラミックス協会
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詳細情報 詳細情報について
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- CRID
- 1390282680262308608
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- NII論文ID
- 130004950781
- 40019536072
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- NII書誌ID
- AA12229489
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- ISSN
- 13486535
- 18820743
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- NDL書誌ID
- 024173471
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可