IR-SNOM Analysis of Occluding Substances in Lumina of Xylem Elements in Sapwood of Quercus serrata Attacked by Platypus quercivorus

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  • YAMAGISHI Takayuki
    Laboratory of Wood Chemistry, Department of Biomaterial Sciences, Graduate School of Agricultural and Life Sciences, The University of Tokyo
  • AIZAWA Kento
    IR & Raman Engineering Division, Jasco Co., Ltd.
  • YAMADA Toshihiro
    The University of Tokyo Chiba Forest, Graduate School of Agricultural and Life Sciences, The University of Tokyo
  • MATSUMOTO Yuji
    Laboratory of Wood Chemistry, Department of Biomaterial Sciences, Graduate School of Agricultural and Life Sciences, The University of Tokyo

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タイトル別名
  • IR-SNOM Analysis of Occluding Substances in Lumina of Xylem Elements in Sapwood of <i>Quercus serrata</i> Attacked by <i>Platypus quercivorus</i>

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A new microspectroscopic technique was applied to the analysis of occluding deposits in xylem elements of Quercus serrata. The production of this substance is believed to be a defense response of the sapwood against fungal infection. An occluding substance about 10 μm across was analyzed by Infrared-Scanning Near-field Optical Microscopy (IR-SNOM), which allows for the measurement of IR spectrum with high spatial resolution. The near-field IR spectrum of an occluding substance was different from those of xylem elements and featured a lack of the clear C–H absorption band that should appear at 3000 – 2850 cm−1. On the other hand, the absorption band of ester bond exhibited a very strong peak. Among the near-field IR spectra of related compounds, a similar ester absorption peak was observed in the spectrum of pectin and tannic acid. The presence of a C–H absorption band as a very week peak was similar to (+)-catechin and tannic acid.

収録刊行物

  • Analytical Sciences

    Analytical Sciences 29 (4), 411-415, 2013

    社団法人 日本分析化学会

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