Three Acylated Glycosidic Acid Methyl Esters and Two Acylated Methyl Glycosides Generated from the Convolvulin Fraction of Seeds of Quamoclit pennata by Treatment with Indium(Ⅲ) Chloride in Methanol
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- Akiyama Kousuke
- School of Agriculture, Tokai University
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- Mineno Tomoko
- Faculty of Pharmacy, Takasaki University of Health and Welfare
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- Okawa Masafumi
- Faculty of Pharmaceutical Sciences, Fukuoka University
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- Kinjo Junei
- Faculty of Pharmaceutical Sciences, Fukuoka University
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- Miyashita Hiroyuki
- Faculty of Pharmaceutical Sciences, Sojo University
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- Yoshimitsu Hitoshi
- Faculty of Pharmaceutical Sciences, Sojo University
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- Nohara Toshihiro
- Faculty of Pharmaceutical Sciences, Sojo University
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- Ono Masateru
- School of Agriculture, Tokai University
書誌事項
- タイトル別名
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- Three Acylated Glycosidic Acid Methyl Esters and Two Acylated Methyl Glycosides Generated from the Convolvulin Fraction of Seeds of <i>Quamoclit pennata</i> by Treatment with Indium(III) Chloride in Methanol
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抄録
Treatment of the ether-insoluble resin glycoside (convolvulin) fraction from seeds of Quamoclit pennata (Convolvulaceae) with indium(III) chloride in methanol provided three oligoglycosides of hydroxy fatty acid (glycosidic acid) methyl esters and two methyl glycosides, which were partially acylated by a glycosidic acid, 7S-hydroxydecanoic acid 7-O-β-D-quinovopyranoside (quamoclinic acid B) and/or two organic acids, (E)-2-methylbut-2-enoic (tiglic) acid and/or 3R-hydroxy-2R-methylbutyric (nilic) acid. Their structures were elucidated on the basis of spectroscopic data and chemical conversions.
収録刊行物
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- CHEMICAL & PHARMACEUTICAL BULLETIN
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CHEMICAL & PHARMACEUTICAL BULLETIN 61 (9), 952-961, 2013
公益社団法人 日本薬学会
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詳細情報 詳細情報について
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- CRID
- 1390001204177989888
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- NII論文ID
- 130003360828
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- NII書誌ID
- AA00602100
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- COI
- 1:STN:280:DC%2BC3sbksFCmsw%3D%3D
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- ISSN
- 13475223
- 00092363
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- NDL書誌ID
- 024791848
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- PubMed
- 23995359
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- PubMed
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可