In-Situ Electron Microscope Observations of Electrochemical Li Deposition/Dissolution with a LiPON Electrolyte

• MOTOYAMA Munekazu

  Department of Materials, Physics and Energy Engineering, Nagoya University JST-ALCA

• EJIRI Makoto

  Department of Materials, Physics and Energy Engineering, Nagoya University JST-ALCA

• IRIYAMA Yasutoshi

  Department of Materials, Physics and Energy Engineering, Nagoya University JST-ALCA

抄録

This paper studies the effect of current density on electrochemical Li deposition/dissolution at glassy solid electrolyte (LiPON) interfaces with a thin-film Cu current collector by in-situ scanning electron microscopy (SEM). The Li nucleation rate and the saturation density of Li nuclei increase with increasing current density. When the current density is smaller than 300 µA cm⁻², Li islands continue to separately grow under a Cu film to the critical sizes to produce small cracks in the Cu film resulting in isolated Li rod growth from the cracks. On the other hand, a current density of 1.0 mA cm⁻² provokes the nucleation of Li islands at a number of sites. They rapidly coalesce under a Cu film in all lateral directions before cracking the Cu film, whereby Li growth is prevented.

収録刊行物

• Electrochemistry

  Electrochemistry 82 (5), 364-368, 2014

  公益社団法人　電気化学会

キーワード

• Li
• Solid-state Electrolyte
• Electrodeposition
• In-situ Scanning Electron Microscopy

詳細情報

• CRID: 1390001206499803136
• NII論文ID: 130004562459
• NII論文ID: 40020051378
• NII書誌ID: AN00151637
• DOI: 10.5796/electrochemistry.82.364
• ISSN: 21862451
• ISSN: 13443542
• NDL書誌ID: 025428564
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I025428564
• Web Site: https://www.jstage.jst.go.jp/article/electrochemistry/82/5/82_13-E00040/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用可