細孔性ネットワーク錯体を用いたS₃分子の単離と粉末X線回折による構造決定

• 大津 博義

  浦項工科大学先端材料科学部

書誌事項

タイトル別名

• Isolation of Labile S₃ Molecule in Porous Coordination Network and its Structure Determination by <i>Ab Initio</i> Powder X-ray Analysis
• 細孔性ネットワーク錯体を用いたS₃分子の単離と粉末X線回折による構造決定
• サイコウセイ ネットワーク サクタイ オ モチイタ S ₃ ブンシ ノ タンリ ト フンマツ Xセン カイセツ ニ ヨル コウゾウ ケッテイ
• Isolation of Labile S3 Molecule in Porous Coordination Network and its Structure Determination by Ab Initio Powder X-ray Analysis

抄録

In this review, we report isolation of unstable tri-sulfur, S₃, in a porous coordination network which is used as a crystalline molecular flask. The ozone-like structure of S₃ in a pore was determined by ab initio X-ray powder diffraction analysis. The S₃ in the pore was interacted with iodine which faces to the pore of the network. The S₃ in the network was quite stable unlike unstable gaseous S₃ molecule because of the S-I interaction in the pore. Furthermore, the S₃ in the network could be transformed to S₆ by mechanical grinding or heating in the presence of NH₄Cl. We will introduce new chemistry of small sulfur based on crystal structure.

収録刊行物

• 日本結晶学会誌

  日本結晶学会誌 56 (5), 323-328, 2014

  日本結晶学会

キーワード

• Earth-Surface Processes

詳細情報

• CRID: 1390282679065713792
• NII論文ID: 130004714203
• NII論文ID: 40020256053
• NII書誌ID: AN00188364
• DOI: 10.5940/jcrsj.56.323
• ISSN: 18845576
• ISSN: 03694585
• NDL書誌ID: 025895407
• Web Site: http://id.ndl.go.jp/bib/025895407
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I025895407
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可