書誌事項
- タイトル別名
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- Highly Efficient and Selective Diastereodifferentiating Organic Photoreactions Using Flow Microreactor
- フローマイクロリアクターを利用した高効率・高選択的なジアステレオ区別有機光反応
- フローマイクロリアクター オ リヨウ シタ コウコウリツ ・ コウセンタクテキ ナ ジアステレオ クベツ ユウキ ヒカリ ハンノウ
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This article describes the highly efficient asymmetric photoreactions using flow microreactor. Organic photochemical reactions are highly effective methods forming complicated or distorted structures that cannot be obtained easily by conventional thermal reactions. On the other hand, photoreactions suffer from low reaction efficiency in common batch reactors owing to low light penetration. To solve this problem, microreactors have recently been fascinated. The asymmetric [2+2] photocycloadditions performed in both hand-made capillary reactors and purchased microreactors, and could be achieved higher diastereoselectivity and productivity than those in batch reactors. Additionally, the Paternò-Büchi type photoreactions in slug flow conditions with organic layer and unreactive layer (water or nitrogen gas) showed the unprecedented enhancement on reaction efficiency. These results demonstrate the good potential of micro flowreactor to achieve the efficient organic photoreactions not only in the lab scale chemistry but also in the process chemistry.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 73 (5), 460-468, 2015
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390001205341694336
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- NII論文ID
- 130005077686
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 026396410
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- 抄録ライセンスフラグ
- 使用不可