Oxidative Intramolecular C-C Bond Formation Reaction of 1,2-Bis(pyren-2-yl)benzene : Synthesis and Characterization of Benzodinaphthopentaphene

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<jats:title>Abstract</jats:title> <jats:p>An intramolecular oxidative C–C bond formation reaction of a 1,2-bis(pyren-2-yl)benzene derivative gave benzodinaphthopentaphene, a new polycyclic aromatic hydrocarbon. Its expanded π-system induced a bathochromic shift in the absorption spectrum and amphoteric multi redox processes in electrochemistry. Furthermore, the [5]helicene moiety of the molecule induced helical chirality.</jats:p>

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