ホイスラー化合物熱電材料の新展開

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  • 西野 洋一
    名古屋工業大学大学院工学研究科未来材料創成工学専攻

書誌事項

タイトル別名
  • New Development of Thermoelectric Materials Based on Heusler Compounds
  • ホイスラー カゴウブツ ネツデンザイリョウ ノ シン テンカイ

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抄録

  The Heusler-type Fe2VAl-based compounds can be a possible candidate for new thermoelectric materials. A significant enhancement in the Seebeck coefficient with both positive and negative sign can be achieved not only by the Fe/V off-stoichiometry combined with doping but also by the V/Al off-stoichiometry even without doping. For the latter alloys, the peak temperature of the Seebeck coefficient increases up to 600 K, and the maximum power factor is 4.3×10−3 for p-type and 6.8×10−3 W/mK2 for n-type, both of which are higher than those of the half-Heusler compound ZrNiSn and Mg2Si compound. A large power factor is required for practical applications of automotive thermoelectric generators. The heavy element Ta doping for the V/Al off-stoichiometric alloys is effective in increasing the dimensionless figure of merit at around 500 K.<br>

収録刊行物

  • 日本金属学会誌

    日本金属学会誌 79 (11), 548-554, 2015

    公益社団法人 日本金属学会

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