NARROWING OF X-RAY DIFFRACTION PEAK OF CLAY-ORGANIC HYBRID FILMS BY SWELLING AND DRYING PROCEDURE

• SUZUKI YASUTAKA

  Graduate School of Medicine, Yamaguchi University

• HIMENO DAISUKE

  Graduate School of Science and Engineering, Yamaguchi University

• TOMINAGA MAKOTO

  Graduate School of Medicine, Yamaguchi University

• TANI SEIJI

  Graduate School of Science and Engineering, Yamaguchi University

• NOZAKI KOJI

  Graduate School of Science and Engineering, Yamaguchi University

• KAWAMATA JUN

  Graduate School of Medicine, Yamaguchi University

抄録

We have found that X-ray diffraction peaks of clay-organic hybrid films were narrowed after swelling followed by removing of solvent. We fabricated hybrid films consisting of natural montmorillonite (Mont), synthetic saponite (SSA) or synthetic stevensite (SST) and a cationic organic molecule. Full width at half maximum (FWHM) of 001 reflection of as-prepared Mont hybrid was 1.58 2θ degree whereas that after swelling and solvent removing procedure was 0.84 2θ degree. This decreasing of FWHM indicated that the improvement of packing order of clay particles in clay-organic hybrid was occurred during swelling and solvent removing procedure. Similar decreasing of FWHM was also found in hybrids consisting of SSA or SST. Improvement of packing order of hybrid was found to accompany suppression of light scattering of hybrid at the same time.

収録刊行物

• Ｃｌａｙ　Ｓｃｉｅｎｃｅ

  Ｃｌａｙ　Ｓｃｉｅｎｃｅ 19 (4), 79-83, 2015

  一般社団法人 日本粘土学会

キーワード

• Clay-organic hybrid
• Smectite
• Swelling

詳細情報

• CRID: 1390282679090030848
• NII論文ID: 110010050733
• NII書誌ID: AA00607148
• DOI: 10.11362/jcssjclayscience.19.4_79
• ISSN: 21863555
• ISSN: 00098574
• NDL書誌ID: 027215518
• Web Site: https://petit.lib.yamaguchi-u.ac.jp/28990
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I027215518
• 本文言語コード: en
• データソース種別:
  • JaLC
  • IRDB
  • NDL
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可