Studies on chain dynamics of poly(alkyl methacrylates) in solutions by the fluorescence depolarization method 蛍光偏光解消法によるポリアルキルメタクリレート鎖の溶液中での分子運動に関する研究
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著者
書誌事項
- タイトル
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Studies on chain dynamics of poly(alkyl methacrylates) in solutions by the fluorescence depolarization method
- タイトル別名
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蛍光偏光解消法によるポリアルキルメタクリレート鎖の溶液中での分子運動に関する研究
- 著者名
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佐々木, 隆, 1960- 高分子構造
- 著者別名
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ササキ, タカシ
- 学位授与大学
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京都大学
- 取得学位
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工学博士
- 学位授与番号
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甲第4684号
- 学位授与年月日
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1991-01-23
注記・抄録
博士論文
目次
- 論文目録 / (0001.jp2)
- Contents / p1 (0005.jp2)
- Chapter 1 General introduction / p1 (0007.jp2)
- 1.1 Problems in the field of polymer chain dynamics / p1 (0007.jp2)
- 1.2 Experimental methods for the study of the local chain dynamics / p6 (0010.jp2)
- 1.3 Motivation and outline / p11 (0012.jp2)
- References / p17 (0015.jp2)
- Chapter 2 Method of fluorescence depolarization / p25 (0019.jp2)
- 2.1 Principle of fluorescence depolarization / p25 (0019.jp2)
- 2.2 Experimental method for the measurement of time-resolved fluorescence depolarization / p29 (0021.jp2)
- 2.3 Data analysis / p38 (0026.jp2)
- 2.4 Measurement by continuous excitation / p42 (0028.jp2)
- References / p43 (0028.jp2)
- Chapter 3 Local chain dynamics of poly(methyl methacrylate) in dilute solutions / p47 (0030.jp2)
- 3.1 Introduction / p47 (0030.jp2)
- 3.2 Theoretical background of polymer chain dynamics / p49 (0031.jp2)
- 3.3 Phenomenological models for local chain dynamics used in this study / p56 (0035.jp2)
- 3.4 Experimental / p66 (0040.jp2)
- 3.5 Results and discussion / p78 (0046.jp2)
- 3.6 Conclusion / p102 (0058.jp2)
- References and notes / p103 (0058.jp2)
- Chapter 4 Local chain dynamics of poly(alkyl methacrylates) in dilute solutions / p111 (0062.jp2)
- 4.1 Introduction / p111 (0062.jp2)
- 4.2 Experimental / p112 (0063.jp2)
- 4.3 Results and discussion / p115 (0064.jp2)
- 4.4 Conformational energy calculations and estimation of the static chain stiffness / p120 (0067.jp2)
- 4.5 Relation between the static and dynamic chain stiffness / p141 (0077.jp2)
- 4.6 Conclusion / p147 (0080.jp2)
- References / p148 (0081.jp2)
- Chapter 5 Local chain dynamics of poly(methyl methacrylate) in nonentangled concen- trated solutions / p151 (0082.jp2)
- 5.1 Introduction / p151 (0082.jp2)
- 5.2 Experimental / p152 (0083.jp2)
- 5.3 Results and discussion / p154 (0084.jp2)
- 5.4 Conclusion / p166 (0090.jp2)
- References / p167 (0090.jp2)
- Chapter 6 Formation and torsion dynamics of the stereocomplex of isotactic and syndio- tactic poly(methyl methacrylates) / p169 (0091.jp2)
- 6.1 Introduction / p169 (0091.jp2)
- 6.2 Formula of the fluorescence emission anisotropy of the twisting stereocomplex / p172 (0093.jp2)
- 6.3 Experimental / p175 (0094.jp2)
- 6.4 Results and discussion / p177 (0095.jp2)
- 6.5 Conclusion / p186 (0100.jp2)
- References / p187 (0100.jp2)
- Chapter 7 On the activation energy of local polymer motions / p191 (0102.jp2)
- 7.1 Introduction / p191 (0102.jp2)
- 7.2 Experimental / p192 (0103.jp2)
- 7.3 Results and discussion / p196 (0105.jp2)
- 7.4 Conclusion / p208 (0111.jp2)
- References / p208 (0111.jp2)
- Appendix Anisotropic rotation of perylene in solution / p211 (0112.jp2)
- Summary / p221 (0117.jp2)
- List of publication / p225 (0119.jp2)