Studies on stereoregular polymerization of aromatic acetylenes characterization of the resulting polymers 芳香族アセチレン類の立体規則性重合と生成ポリマーのキャラクタリゼーションに関する研究

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著者

    • 楊, 武 ヤン, ウー

書誌事項

タイトル

Studies on stereoregular polymerization of aromatic acetylenes characterization of the resulting polymers

タイトル別名

芳香族アセチレン類の立体規則性重合と生成ポリマーのキャラクタリゼーションに関する研究

著者名

楊, 武

著者別名

ヤン, ウー

学位授与大学

北海道大学

取得学位

工学博士

学位授与番号

甲第2923号

学位授与年月日

1991-03-25

注記・抄録

博士論文

目次

  1. TABLE OF CONTENTS / p2 (0004.jp2)
  2. Chapter 1 / p1 (0009.jp2)
  3. Introduction / p1 (0009.jp2)
  4. 1-1 Statement of the problem and the project / p1 (0009.jp2)
  5. 1-2 General properties of polyacetylenes / p2 (0010.jp2)
  6. 1-3 History of polyacetylenes / p6 (0014.jp2)
  7. Chapter 2 / p10 (0018.jp2)
  8. Synthesis of Aromatic Acetylene Monomers / p10 (0018.jp2)
  9. 2-1 Introduction / p10 (0018.jp2)
  10. 2-2 Derivation of acetylenes monomers from styrenes (method 1) / p10 (0018.jp2)
  11. 2-3 Derivation of acetylene monomer from cinnamic acids (method 2) / p11 (0019.jp2)
  12. 2-4 Synthesis of acetylene monomers by coupling reaction (method 3) / p12 (0020.jp2)
  13. 2-5 Synthesis of deuterated acetylene monomer / p15 (0023.jp2)
  14. Chapter 3 / p21 (0029.jp2)
  15. Polymerization of Substituted Phenylacetylene with GroupVIII Transition Metal Complex Catalysts / p21 (0029.jp2)
  16. 3-1 Introduction / p21 (0029.jp2)
  17. 3-2 General properties of [Rh(L-L)Cl]₂ type complexes / p23 (0031.jp2)
  18. 3-3 Experimental / p26 (0034.jp2)
  19. 3-4 Catalytic activity of the complex in the polymerization / p27 (0035.jp2)
  20. 3-5 Reactivity of monomer / p37 (0045.jp2)
  21. 3-6 Conclusion / p42 (0050.jp2)
  22. Chapter 4 / p46 (0054.jp2)
  23. Copolymerization and Gel formation / p46 (0054.jp2)
  24. 4-1 Introduction / p46 (0054.jp2)
  25. 4-2 Experimental / p46 (0054.jp2)
  26. 4-3 Influence of catalyst concentration on gelation / p46 (0054.jp2)
  27. 4-4 Influence of substitution position and other halo-substitutents on the gel formation / p48 (0056.jp2)
  28. 4-5 Coplymerization and gel formation / p49 (0057.jp2)
  29. 4-6 The mechanism of gel formation / p54 (0062.jp2)
  30. 4-7 Conclusion / p56 (0064.jp2)
  31. Chapter 5 / p58 (0066.jp2)
  32. Living polymerization / p58 (0066.jp2)
  33. 5-1 Introduction / p58 (0066.jp2)
  34. 5-2 Experimental / p58 (0066.jp2)
  35. 5-3 Cocatalytic effect of TEA and monomer choosing for the living polymerization / p59 (0067.jp2)
  36. 5-4 General properties of the new living polymerization system / p62 (0070.jp2)
  37. 5-5 Influence of reaction temperature / p66 (0074.jp2)
  38. 5-6 Influence of [TEA]/[Cat.] ratio / p67 (0075.jp2)
  39. 5-7 Influence of catalyst concentration / p69 (0077.jp2)
  40. 5-8 Conclusion / p71 (0079.jp2)
  41. Chapter 6 / p74 (0082.jp2)
  42. Polymerization mechanism in the presence of rhodium complexes / p74 (0082.jp2)
  43. 6-1 Introduction / p74 (0082.jp2)
  44. 6-2 Experimental / p74 (0082.jp2)
  45. 6-3 Differences between the polymerization initiated by W,Mo based catalysts and the rhodium complex catalysts / p75 (0083.jp2)
  46. 6-4 Kern and Furlani's mechanism and their verification / p77 (0085.jp2)
  47. 6-5 ¹H NMR study of the polymerization mechanism / p83 (0091.jp2)
  48. 6-6 Reaction rate and hydrogen atom exchange in the polymerization / p88 (0096.jp2)
  49. 6-7 Conclusion / p94 (0102.jp2)
  50. Chapter 7 / p97 (0105.jp2)
  51. Polymerization of Aromatic Acetylenes with WC1₆ and M0Cl₅ and by Thermal Initiation / p97 (0105.jp2)
  52. 7-1 Introduction / p97 (0105.jp2)
  53. 7-2 Exerimental / p97 (0105.jp2)
  54. 7-3 Activity of M0Cl₅ and WC1₆ / p99 (0107.jp2)
  55. 7-4 Time dependence of molecular weight, polymer yield and monomer conversion / p102 (0110.jp2)
  56. 7-5 Influence of catalyst concentration / p104 (0112.jp2)
  57. 7-6 Influence of temperature on the polymerization / p106 (0114.jp2)
  58. 7-7 Polymerization mechanism / p107 (0115.jp2)
  59. 7-8 Thermal polymerization of p-nitrophenylacetylene / p109 (0117.jp2)
  60. 7-9 Conclusion / p113 (0121.jp2)
  61. Chapter 8 / p116 (0124.jp2)
  62. General properties of the polymers synthesized with Rh complexes / p116 (0124.jp2)
  63. 8-1 Introduction / p116 (0124.jp2)
  64. 8-2 Polymers prepared in heterogeneous system by use of Rh complexes / p116 (0124.jp2)
  65. 8-3 Polymers prepared in homogeneous system by way of Rh complexes / p117 (0125.jp2)
  66. 8-4 Polymers synthesized with WC1₆ and M0Cl₅ / p117 (0125.jp2)
  67. 8-5 Thermal and solvent induced isomerization / p118 (0126.jp2)
  68. 8-6 Crystallization / p118 (0126.jp2)
  69. 8-7 Gelation and gel film / p121 (0129.jp2)
  70. 8-8 Magnetic properties / p121 (0129.jp2)
  71. 8-9 Electrical properties / p123 (0131.jp2)
  72. 8-10 Conclusion / p123 (0131.jp2)
  73. Chapter 9 / p127 (0135.jp2)
  74. Spectroscopic study on the polymer structure / p127 (0135.jp2)
  75. 9-1 Introduction / p127 (0135.jp2)
  76. 9-2 Experimental / p127 (0135.jp2)
  77. 9-3 IR study on the polymer structure / p127 (0135.jp2)
  78. 9-4 NMR study on the polymer structure / p141 (0149.jp2)
  79. 9-5 UV study on the polymer structure / p151 (0159.jp2)
  80. 9-6 Conclusion / p157 (0165.jp2)
  81. Chapter 10 / p160 (0168.jp2)
  82. Magnetic and electrical properties / p160 (0168.jp2)
  83. 10-1 Introduction / p160 (0168.jp2)
  84. 10-2 Experimental / p160 (0168.jp2)
  85. 10-3 Radical concentration / p160 (0168.jp2)
  86. 10-4 Hyperfine structure / p166 (0174.jp2)
  87. 10-5 Doping properties / p170 (0178.jp2)
  88. 10-6 Electrical properties / p172 (0180.jp2)
  89. 10-7 Conclusion / p174 (0182.jp2)
  90. Chapter 11 / p176 (0184.jp2)
  91. Summary / p176 (0184.jp2)
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各種コード

  • NII論文ID(NAID)
    500000073625
  • NII著者ID(NRID)
    • 8000000073822
  • DOI(NDL)
  • NDL書誌ID
    • 000000237939
  • データ提供元
    • NDL ONLINE
    • NDLデジタルコレクション

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