New and effective route to the fluoro analogs of amino acids via regioselective hydroformylation with homogeneous catalyst 均一系触媒による位置選択的ヒドロホルミル化反応を用いた効率的な含フッ素アミノ酸の新規合成法
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著者
書誌事項
- タイトル
-
New and effective route to the fluoro analogs of amino acids via regioselective hydroformylation with homogeneous catalyst
- タイトル別名
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均一系触媒による位置選択的ヒドロホルミル化反応を用いた効率的な含フッ素アミノ酸の新規合成法
- 著者名
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加登, 幸治
- 著者別名
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カト, コウジ
- 学位授与大学
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上智大学
- 取得学位
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理学博士
- 学位授与番号
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乙第74号
- 学位授与年月日
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1991-03-12
注記・抄録
博士論文
目次
- List of Content / (0004.jp2)
- Abstract / p1 (0014.jp2)
- Chapter1 Synthesis of fluorinated compounds and their biological activities / p3 (0016.jp2)
- Why the fluoro analogs of biologically active compounds show the characteristic activities / p5 (0018.jp2)
- How to introduce fluorine atoms into organic molecules / p16 (0029.jp2)
- How to solve the problems for the syntheses of fluoro amino acids / p26 (0039.jp2)
- Purpose of this study / p31 (0044.jp2)
- References and notes / p33 (0046.jp2)
- Chapter2 Hydroformylation of fluoro olefins, catalyzed group VIII transition-metal catalysts Crucial factors for extremely high regioselectivity / p38 (0051.jp2)
- Introduction / p39 (0052.jp2)
- Results and discussion / p40 (0053.jp2)
- Experimental / p60 (0073.jp2)
- References and notes / p69 (0082.jp2)
- Chapter3 Homogeneous catalysis of mixed-metal systems highly regioselective hydroformylationamidocarbonylation of fluoro olefin catalyzed by Co-Rh mixed metal systems / p73 (0086.jp2)
- Introduction / p74 (0087.jp2)
- Results and discussion / p77 (0090.jp2)
- Experimental / p101 (0114.jp2)
- References and notes / p107 (0120.jp2)
- Chapter4 New and effective routes to fluoro analogs of aliphatic amino acids / p114 (0127.jp2)
- Introduction / p115 (0128.jp2)
- Results and discussion / p116 (0129.jp2)
- Experimental / p128 (0141.jp2)
- References and notes / p153 (0166.jp2)
- Chapter5 Synthesis of tetrafluoro analogs of tryptophan and related compounds / p157 (0170.jp2)
- Introduction / p158 (0171.jp2)
- Results and discussion / p159 (0172.jp2)
- Experimental / p164 (0177.jp2)
- References and notes / p179 (0192.jp2)
- Chapter6 The synthesis of fluoro analogs of Enkephalin / p181 (0194.jp2)
- Introduction / p182 (0195.jp2)
- Results and discussion / p184 (0197.jp2)
- Experimental / p187 (0200.jp2)
- References and notes / p193 (0206.jp2)
- Summary / p195 (0208.jp2)
- General discussion / p199 (0212.jp2)
- Acknowledgment / p207 (0220.jp2)