Preparation of the polymethacrylates with controlled structures through the detailed analysis of polymerization products メタクリル酸エステル重合体の精密構造解析と構造規制

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Author

    • 右手, 浩一 ウテ, コウイチ

Bibliographic Information

Title

Preparation of the polymethacrylates with controlled structures through the detailed analysis of polymerization products

Other Title

メタクリル酸エステル重合体の精密構造解析と構造規制

Author

右手, 浩一

Author(Another name)

ウテ, コウイチ

University

大阪大学

Types of degree

工学博士

Grant ID

乙第5239号

Degree year

1991-01-18

Note and Description

博士論文

Table of Contents

  1. CONTENTS / (0004.jp2)
  2. General Introduction / p1 (0005.jp2)
  3. References / p12 (0011.jp2)
  4. CHAPTER1.Studies on the Anionic Polymerizations of Methyl Methacrylate Using Totally Deuterated Monomer and Undeuterated or Partially Deuterated Initiator / p14 (0012.jp2)
  5. 1.1 Introduction / p14 (0012.jp2)
  6. 1.2 Structures of the PMMAs Prepared with Butylmagnesium Chloride and with Several Other Anionic Initiators / p15 (0012.jp2)
  7. 1.3 Polymerizations of MMA-d8 with Butyllithium-1,1-d2 and Butylmagnesiutn-1,1-d2 Chloride / p26 (0018.jp2)
  8. 1.4 Polymerization of MMA-d8 with t-Butylmagnesium Bromide and Formation of a Cyclic Ketone Terminal in Living PMMA Anions / p41 (0025.jp2)
  9. 1.5 Experimental Part / p45 (0027.jp2)
  10. References / p47 (0028.jp2)
  11. CHAPTER2.Living and Highly Isotactic Polymerization of Methyl Methacrylate / p49 (0029.jp2)
  12. 2.1 Introduction / p49 (0029.jp2)
  13. 2.2 Living and Highly Isotactic Polymerization of MMA with t-Butylmagnesium Bromide in Toluene / p50 (0030.jp2)
  14. 2.3 Preparation of Block and Random Copolymers of Methacrylates with High Stereoregularity / p59 (0034.jp2)
  15. 2.4 Stereochemistry of the Oligomerization of MMA by t-Butylmagnesium Bromide in Toluene at -78℃ / p64 (0037.jp2)
  16. 2.5 Two-dimensional NMR Spectra of the Isotactic PMMA Prepared with f-Butylmagnesium Bromide and Detailed Examination of Tacticity / p68 (0039.jp2)
  17. 2.6 Experimental Part / p83 (0046.jp2)
  18. References / p85 (0047.jp2)
  19. CHAPTER3.Stereoregular Oligomers of Methyl Methacrylate / p87 (0048.jp2)
  20. 3.1 Introduction / p87 (0048.jp2)
  21. 3.2 ¹H and ¹³C NMR Spectra of the Pure lsotactic andPure Syndiotactic Oligomers from Dimer to Octamer / p89 (0049.jp2)
  22. 3.3 Structure of the lsotactic Trimer in Crystal / p105 (0057.jp2)
  23. 3.4 SupercriticalFluidChromatography oftheStereoregular Oligomers of MMA / p112 (0061.jp2)
  24. 3.5 Experimental Part / p118 (0064.jp2)
  25. References / p120 (0065.jp2)
  26. CHAPTER4.Analysis of Polymers by On-line GPC/NMR / p122 (0066.jp2)
  27. 4.1 Introduction / p122 (0066.jp2)
  28. 4.2 Instrumentation for the On-line GPC/NMR Method / p123 (0066.jp2)
  29. 4.3 Determination of Molecular Weight and Its Distribution by Absolute Calibration Method Using the PMMAs with Weii-Defined Structure / p125 (0067.jp2)
  30. 4.4 Molecular Weight Dependence of Tacticity of the PMMAs Prepared by Anionic Initiators / p131 (0070.jp2)
  31. 4.5 Molecular Weight Dependence of Chemical Composition of the Copolymers of Methacrylates / p137 (0073.jp2)
  32. 4.6 On-line GPC/NMR Analysis of the Mixture of Chloral Oligomers / p145 (0077.jp2)
  33. 4.7 Experimental Part / p149 (0079.jp2)
  34. References / p150 (0080.jp2)
  35. Publication List / p151 (0080.jp2)
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Codes

  • NII Article ID (NAID)
    500000075836
  • NII Author ID (NRID)
    • 8000000076036
  • DOI(NDL)
  • Text Lang
    • eng
  • NDLBibID
    • 000000240150
  • Source
    • Institutional Repository
    • NDL ONLINE
    • NDL Digital Collections

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