Studies on polyprenyl diphosphate synthases : Reaction mechanism and application to organic synthesis ポリプレニル二リン酸合成酵素の研究 : 反応機構と有機合成への応用

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著者

    • 大沼, 信一 オオヌマ, シンイチ

書誌事項

タイトル

Studies on polyprenyl diphosphate synthases : Reaction mechanism and application to organic synthesis

タイトル別名

ポリプレニル二リン酸合成酵素の研究 : 反応機構と有機合成への応用

著者名

大沼, 信一

著者別名

オオヌマ, シンイチ

学位授与大学

東北大学

取得学位

理学博士

学位授与番号

甲第4323号

学位授与年月日

1991-03-28

注記・抄録

博士論文

目次

  1. CONTENTS / (0003.jp2)
  2. INTRODUCTION / p1 (0007.jp2)
  3. Chapter I Characterization of Long Chain E-Prenyl Diphosphate Synthases / p10 (0016.jp2)
  4. Section I-1 Purification of Solanesyl Diphosphate Synthase and its Stimulation by an Activation Factor / p11 (0017.jp2)
  5. INTRODUCTION / p11 (0017.jp2)
  6. EXPERIMENTAL PROCEDURES / p13 (0019.jp2)
  7. RESULTS / p17 (0023.jp2)
  8. Section I-2 Characterization of Octaprenyl Diphosphate Synthase / p42 (0048.jp2)
  9. INTRODUCTION / p42 (0048.jp2)
  10. EXPERIMENTAL PROCEDURES / p43 (0049.jp2)
  11. RESULTS / p46 (0052.jp2)
  12. Section I-3 Effects of the Activation Factor on Other Polyprenyl Diphosphate Synthases / p60 (0066.jp2)
  13. INTRODUCTION / p60 (0066.jp2)
  14. EXPERIMENTAL PROCEDURES / p62 (0068.jp2)
  15. RESULTS / p65 (0071.jp2)
  16. DISCUSSION / p75 (0081.jp2)
  17. Chapter II Chain Length Distribution of the Products Formed by Polyprenyl Diphosphate Synthase Reaction / p81 (0087.jp2)
  18. Section II-1 Effects of the Concentrations of Mg²⁺,IPP and Allylic Substrate on the Chain Lengths of the Products / p82 (0088.jp2)
  19. INTRODUCTION / p82 (0088.jp2)
  20. EXPERIMENTAL PROCEDURES / p84 (0090.jp2)
  21. RESULTS / p87 (0093.jp2)
  22. DISCUSSION / p111 (0117.jp2)
  23. Section II-2 Effects of the Species of Divalent Metal Ion on the Chain Lengths of the Products / p113 (0119.jp2)
  24. INTRODUCTION / p113 (0119.jp2)
  25. EXPERIMENTAL PROCEDURES / p114 (0120.jp2)
  26. RESULTS / p117 (0123.jp2)
  27. DISCUSSION / p156 (0162.jp2)
  28. Chapter III Polyprenyl Diphosphate Synthase Reaction with Artificial Substrate Homologues / p158 (0164.jp2)
  29. Section III-1 The Enantiomeric Purities of(S)-and(R)-4-Methylfarnesols Synthesized from Artificial Substrates by Means of Farnesyl Diphosphate Synthase Reaction / p159 (0165.jp2)
  30. INTRODUCTION / p159 (0165.jp2)
  31. EXPERIMENTAL PROCEDURES / p161 (0167.jp2)
  32. RESULTS AND DISCUSSION / p165 (0171.jp2)
  33. Section III-2 Undecaprenyl Diphosphate Synthase Reaction with Artificial Substrate Homologues / p170 (0176.jp2)
  34. INTRODUCTION / p170 (0176.jp2)
  35. EXPERIMENTAL PROCEDURES / p172 (0178.jp2)
  36. RESULTS / p185 (0191.jp2)
  37. DISCUSSION / p193 (0199.jp2)
  38. Section III-3 Kinetic Studies on the Prenyl Chain Elongation by Undecaprenyl Diphosphate Synthase with Artificial Substrate Homologues / p195 (0201.jp2)
  39. INTRODUCTION / p195 (0201.jp2)
  40. EXPERIMENTAL PROCEDURES / p196 (0202.jp2)
  41. RESULTS / p197 (0203.jp2)
  42. DISCUSSION / p200 (0206.jp2)
  43. Section III-4 Solanesyl Diphosphate Synthase Reaction with Artificial Substrate Homologues / p203 (0209.jp2)
  44. INTRODUCTION / p203 (0209.jp2)
  45. EXPERIMENTAL PROCEDURES / p205 (0211.jp2)
  46. RESULTS / p212 (0218.jp2)
  47. DISCUSSION / p239 (0245.jp2)
  48. Section III-5 Octaprenyl-,Decaprenyl-,and Hexaprenyl Diphosphate Synthase Reactions with Artificial Substrate Homologues / p243 (0249.jp2)
  49. INTRODUCTION / p243 (0249.jp2)
  50. EXPERIMENTAL PROCEDURES / p245 (0251.jp2)
  51. RESULTS / p251 (0257.jp2)
  52. DISCUSSION / p279 (0285.jp2)
  53. Section III-6 Enzymatic Synthesis of Glycinoprenols / p281 (0287.jp2)
  54. INTRODUCTION / p281 (0287.jp2)
  55. EXPERIMENTAL PROCEDURES / p283 (0289.jp2)
  56. RESULTS and DISCUSSION / p284 (0290.jp2)
  57. SUMMARY / p289 (0295.jp2)
  58. REFERENCES / p295 (0301.jp2)
  59. ACKNOWLEDGMENTS / p304 (0310.jp2)
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各種コード

  • NII論文ID(NAID)
    500000076703
  • NII著者ID(NRID)
    • 8000000076906
  • DOI(NDL)
  • NDL書誌ID
    • 000000241017
  • データ提供元
    • NDL-OPAC
    • NDLデジタルコレクション
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