Studies on the association modes assumed by d-(R,R)-tartrate anion with optically active tris(diamine) metal complex cations with bulky substituents on chelate rings d-酒石酸陰イオンとキレート環に嵩高い置換基を有する光学活性トリスジアミン金属錯体陽イオンとの会合様式に関する研究

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著者

    • 水田, 勉 ミズタ, ツトム

書誌事項

タイトル

Studies on the association modes assumed by d-(R,R)-tartrate anion with optically active tris(diamine) metal complex cations with bulky substituents on chelate rings

タイトル別名

d-酒石酸陰イオンとキレート環に嵩高い置換基を有する光学活性トリスジアミン金属錯体陽イオンとの会合様式に関する研究

著者名

水田, 勉

著者別名

ミズタ, ツトム

学位授与大学

広島大学

取得学位

理学博士

学位授与番号

乙第2141号

学位授与年月日

1991-03-18

注記・抄録

博士論文

目次

  1. CONTENTS / (0008.jp2)
  2. Chapter1 Introduction / p1 (0011.jp2)
  3. Chapter2 Face-to-Face Contact Mode with lel₃-Tris(trans-cyclo-hexanediamine)cobalt(III)Cation / p9 (0019.jp2)
  4. 2-1 Introduction / p10 (0020.jp2)
  5. 2-2 Crystal Structures of the Diastereomeric Salt Pair / p11 (0021.jp2)
  6. 2-3 Chromatographic Behavior / p24 (0034.jp2)
  7. 2-4 Conformation of the d-Tartrate Ion / p27 (0037.jp2)
  8. 2-5 Ab Initio Calculations of the d-Tartrate Ion / p30 (0040.jp2)
  9. 2-6 Mechanism of Chiral Discrimination / p34 (0044.jp2)
  10. 2-7 Experimental Section / p37 (0047.jp2)
  11. Chapter3 Face-to-Face Contact Mode with ob₃-Tris(trans-cyclo-hexanediamine)cobalt(III)Cation / p46 (0056.jp2)
  12. 3-1 Introduction / p47 (0057.jp2)
  13. 3-2 Crystal Structure of A-ob₃-〔Co(R,R-chxn)₃〕Cl(d-tart)・3.5H₂O / p52 (0062.jp2)
  14. 3-3 Experimental Section / p61 (0071.jp2)
  15. Chapter4 Chiral Discrimination of the Facial Isomer of the Tris((R,S)-l,2-cyclohexanediamine)cobalt(III)Cation with d-Tartrate Anion / p66 (0076.jp2)
  16. 4-1 Introduction / p67 (0077.jp2)
  17. 4-2 Crystal Structure of △-fac-〔Co(cis-chxn)₃〕(Cl0₄)(d-tart)・mH₂O / p70 (0080.jp2)
  18. 4-3 Crystal Structure of △-fac-〔Co(cis-chxn)₃〕Cl(d-tart)・nH₂O / p87 (0097.jp2)
  19. 4-4 Elution Order in Chromatography / p95 (0105.jp2)
  20. 4-5 Experimental Section / p97 (0107.jp2)
  21. Chapter5 Face-to-Face Contact Mode with the Divalent Complex Cation / p106 (0116.jp2)
  22. 5-1 Introduction / p107 (0117.jp2)
  23. 5-2 Contact Modes in the Diastereomeric Salts 1 and 2 / p108 (0118.jp2)
  24. 5-3 Comparison of Packing Modes / p113 (0123.jp2)
  25. 5-4 Experimental Section / p119 (0129.jp2)
  26. Summary / p135 (0145.jp2)
  27. Structural Study of Optical Resolution.XIII. The Crystal Structures of the Racemic〔Δ,Λ-d,1〕and the Optically-active〔Δ-d〕 Tartrate Salts of the Tris(ethylenediamine)nickel(II) Complex / p11 (0150.jp2)
  28. Crystal Structures of the Racemic Tartrate and the Two d-Tartrate Salts of the Tris(ethylenediamine)cobalt(III)Complex / (0155.jp2)
  29. A transition-metal diaminophosphonate complex:synthesis and structure of〔(η⁵-C₅H₅)(CO)₂Fe{P(O)(NEt₂)₂}〕₂FeCl₂ / p333 (0159.jp2)
  30. A Novel Structure of Spontaneously Resolved Germanium(IV) Complex with Ethylenediaminetriacetatemonoacetic Acid (Hedta) / p65 (0164.jp2)
  31. The Molecular Structure of the trans〔O₅〕Isomer of (Ethylenediamine-N,N'-diacetato-/N,N'-di-3-propionato〕cobaltate(III),trans〔O₅〕-〔Co(eddda)〕⁻Determined by X-ray Analysis and its Structural Comparison with some Metal(III) Complexes of Related Ligands / (0168.jp2)
  32. The ligand field stabilization effect on the metal-ligand bond distances in octahedral metal complexes with edta-type ligands.Redetermination of the molecular structure of (ethylenediaminetriacetatoacetic acid)-(aqua)iron(III),〔Fe(Hedta)(H₂O)〕 / p121 (0172.jp2)
  33. Rcaction of the Iron I'hosphonatc (η⁵-C₅II₅)(CO)₂Fc{P(O)(NEt₂)(OMc)} with Boron Trihaidcs.Prcparation,X-ray Structure Analysis,and Rcactivity of the Iron Chloro-substituted Phosphonatc Complcx / (0175.jp2)
  34. Structural Study of Optical Resolution. 14. Highly Efficient Chirai Discrimination of the lel₃-Tris(trance-1,2-cyclohexanediamine)cobalt(III) Ion Attained with the d-(R,R)-Tartrate Ion Assuming an Anomalous Conformation / p3020 (0182.jp2)
  35. A Hydrogen-Bonding Mode in the Ion Association of the d-Tartrate Anion with the A-ob₃-Tris((1R,2R)-diaminocyclohexane)cobalt(III) Cation / (0186.jp2)
  36. Structural Study of Optical Resolution.XV.Chiral Discrimination of the Facial Isomer of the Tris((R,S)-1,2-cyclohcxancdiaminc)cobalt(III)Cation with(R,R)-Tartratc Anlon / (0189.jp2)
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各種コード

  • NII論文ID(NAID)
    500000077224
  • NII著者ID(NRID)
    • 8000000077427
  • DOI(NDL)
  • NDL書誌ID
    • 000000241538
  • データ提供元
    • NDL-OPAC
    • NDLデジタルコレクション
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