Studies on generation and reactions of perfluoroenolates ペルフルオロエノラートの生成と反応に関する研究

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著者

    • 銭, 承平 チェン, チョンピン

書誌事項

タイトル

Studies on generation and reactions of perfluoroenolates

タイトル別名

ペルフルオロエノラートの生成と反応に関する研究

著者名

銭, 承平

著者別名

チェン, チョンピン

学位授与大学

東京工業大学

取得学位

工学博士

学位授与番号

甲第2265号

学位授与年月日

1991-03-26

注記・抄録

博士論文

目次

  1. 論文目録 / (0002.jp2)
  2. CONTENTS / (0004.jp2)
  3. Chapter1 General lntroduction / p1 (0008.jp2)
  4. References / p10 (0017.jp2)
  5. Chapter2 Chemistry of Ketone Perfluoroenolates(Part 1):Regio-and Stereoselective Generations of F-Enolates / p12 (0019.jp2)
  6. Summary / p12 (0019.jp2)
  7. 2-1 Introduction / p13 (0020.jp2)
  8. 2-2 Facile Generations of Metal F-Propen-2-olates(Parent F-Enolate) / p14 (0021.jp2)
  9. 2-3 Regio-and Stereoselective Generations of β-CF₃-Substituted F-Enolates / p19 (0026.jp2)
  10. 2-4 Regiospecific Generations of"Terminal"F-Enolates / p24 (0031.jp2)
  11. References / p26 (0033.jp2)
  12. Experimental / p27 (0034.jp2)
  13. Chapter3 Chemistry of Ketone Perfluoroenolates(Part 2):Unique Reactivities of F-Enolates / p35 (0042.jp2)
  14. Summary / p35 (0042.jp2)
  15. 3-1 Introduction / p36 (0043.jp2)
  16. 3-2 "Triple"Reactivity of Lithium F-Propen-2-olate(Parent F-Enolate) / p36 (0043.jp2)
  17. 3-3 Unique Reactivities of β-CF₃-Substituted F-Enolate / p44 (0051.jp2)
  18. 3-4 Discussion Based on Theoretical Calculations on F-Enolates / p46 (0053.jp2)
  19. 3-5 Reactivities of"Terminal"F-Enolates / p49 (0056.jp2)
  20. 3-6 Reactions of F-Enol Silyl Ether / p51 (0058.jp2)
  21. 3-7 Synthetic Utility / p53 (0060.jp2)
  22. References / p56 (0063.jp2)
  23. Experimental / p57 (0064.jp2)
  24. Chapter4 Chemistry of Ketone Perfluoroenolates(Part 3):Reactivities of β-Alkyl Substituted F-Enolates / p85 (0092.jp2)
  25. Summary / p85 (0092.jp2)
  26. 4-1 Introduction / p86 (0093.jp2)
  27. 4-2 Unique Reactivity Patterns of β-Hydro-, p-Butyl- and β-Phenyl- F-Enolates / p86 (0093.jp2)
  28. 4-3 Relative Nucleophilic Reactivity of β-Substituted F-Enolates / p89 (0096.jp2)
  29. 4-4 Discussion Based on Theoretical Calculation on β-Hydro- F-Enolate / p91 (0098.jp2)
  30. Experimental / p94 (0101.jp2)
  31. Chapter5 Chemistry of Lithium Ester Perfluoroenolate / p101 (0108.jp2)
  32. Summary / p101 (0108.jp2)
  33. 5-1 Introduction / p102 (0109.jp2)
  34. 5-2 Aldol Reactions with Lithium Ester F-Enolate 2 / p103 (0110.jp2)
  35. 5-2 Other C-C Bond Formations with Lithium Ester F-Enolate 2 / p104 (0111.jp2)
  36. References / p106 (0113.jp2)
  37. Experimental / p107 (0114.jp2)
  38. Chapter6 Claisen Rearrangement of Perfluoroenol Allyl Ether Systems / p115 (0122.jp2)
  39. Summary / p115 (0122.jp2)
  40. 6-1 Introduction / p116 (0123.jp2)
  41. 6-2 Claisen Rearrangement of F-Enol Ethers / p117 (0124.jp2)
  42. 6-3 Claisen Rearrangement of β-Alkyl Substituted F-Enol Ethers / p118 (0125.jp2)
  43. 6-4 Mechanistic Discussion / p120 (0127.jp2)
  44. 6-5 Synthetic Utilities / p122 (0129.jp2)
  45. References / p124 (0131.jp2)
  46. Experimental / p125 (0132.jp2)
  47. Chapter7 Conclusion / p134 (0141.jp2)
  48. Publications / p142 (0149.jp2)
  49. Oral Presentations / p143 (0150.jp2)
  50. Acknowledgment / (0152.jp2)
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各種コード

  • NII論文ID(NAID)
    500000077940
  • NII著者ID(NRID)
    • 8000000078144
  • DOI(NDL)
  • NDL書誌ID
    • 000000242254
  • データ提供元
    • NDL-OPAC
    • NDLデジタルコレクション
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