Studies on generation and reactions of perfluoroenolates ペルフルオロエノラートの生成と反応に関する研究
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著者
書誌事項
- タイトル
-
Studies on generation and reactions of perfluoroenolates
- タイトル別名
-
ペルフルオロエノラートの生成と反応に関する研究
- 著者名
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銭, 承平
- 著者別名
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チェン, チョンピン
- 学位授与大学
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東京工業大学
- 取得学位
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工学博士
- 学位授与番号
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甲第2265号
- 学位授与年月日
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1991-03-26
注記・抄録
博士論文
目次
- 論文目録 / (0002.jp2)
- CONTENTS / (0004.jp2)
- Chapter1 General lntroduction / p1 (0008.jp2)
- References / p10 (0017.jp2)
- Chapter2 Chemistry of Ketone Perfluoroenolates(Part 1):Regio-and Stereoselective Generations of F-Enolates / p12 (0019.jp2)
- Summary / p12 (0019.jp2)
- 2-1 Introduction / p13 (0020.jp2)
- 2-2 Facile Generations of Metal F-Propen-2-olates(Parent F-Enolate) / p14 (0021.jp2)
- 2-3 Regio-and Stereoselective Generations of β-CF₃-Substituted F-Enolates / p19 (0026.jp2)
- 2-4 Regiospecific Generations of"Terminal"F-Enolates / p24 (0031.jp2)
- References / p26 (0033.jp2)
- Experimental / p27 (0034.jp2)
- Chapter3 Chemistry of Ketone Perfluoroenolates(Part 2):Unique Reactivities of F-Enolates / p35 (0042.jp2)
- Summary / p35 (0042.jp2)
- 3-1 Introduction / p36 (0043.jp2)
- 3-2 "Triple"Reactivity of Lithium F-Propen-2-olate(Parent F-Enolate) / p36 (0043.jp2)
- 3-3 Unique Reactivities of β-CF₃-Substituted F-Enolate / p44 (0051.jp2)
- 3-4 Discussion Based on Theoretical Calculations on F-Enolates / p46 (0053.jp2)
- 3-5 Reactivities of"Terminal"F-Enolates / p49 (0056.jp2)
- 3-6 Reactions of F-Enol Silyl Ether / p51 (0058.jp2)
- 3-7 Synthetic Utility / p53 (0060.jp2)
- References / p56 (0063.jp2)
- Experimental / p57 (0064.jp2)
- Chapter4 Chemistry of Ketone Perfluoroenolates(Part 3):Reactivities of β-Alkyl Substituted F-Enolates / p85 (0092.jp2)
- Summary / p85 (0092.jp2)
- 4-1 Introduction / p86 (0093.jp2)
- 4-2 Unique Reactivity Patterns of β-Hydro-, p-Butyl- and β-Phenyl- F-Enolates / p86 (0093.jp2)
- 4-3 Relative Nucleophilic Reactivity of β-Substituted F-Enolates / p89 (0096.jp2)
- 4-4 Discussion Based on Theoretical Calculation on β-Hydro- F-Enolate / p91 (0098.jp2)
- Experimental / p94 (0101.jp2)
- Chapter5 Chemistry of Lithium Ester Perfluoroenolate / p101 (0108.jp2)
- Summary / p101 (0108.jp2)
- 5-1 Introduction / p102 (0109.jp2)
- 5-2 Aldol Reactions with Lithium Ester F-Enolate 2 / p103 (0110.jp2)
- 5-2 Other C-C Bond Formations with Lithium Ester F-Enolate 2 / p104 (0111.jp2)
- References / p106 (0113.jp2)
- Experimental / p107 (0114.jp2)
- Chapter6 Claisen Rearrangement of Perfluoroenol Allyl Ether Systems / p115 (0122.jp2)
- Summary / p115 (0122.jp2)
- 6-1 Introduction / p116 (0123.jp2)
- 6-2 Claisen Rearrangement of F-Enol Ethers / p117 (0124.jp2)
- 6-3 Claisen Rearrangement of β-Alkyl Substituted F-Enol Ethers / p118 (0125.jp2)
- 6-4 Mechanistic Discussion / p120 (0127.jp2)
- 6-5 Synthetic Utilities / p122 (0129.jp2)
- References / p124 (0131.jp2)
- Experimental / p125 (0132.jp2)
- Chapter7 Conclusion / p134 (0141.jp2)
- Publications / p142 (0149.jp2)
- Oral Presentations / p143 (0150.jp2)
- Acknowledgment / (0152.jp2)