Nuclear magnetic resonance studies on the substituent group distribution intramolecular hydrogen bond nature in cellulose derivatives and their solubility behavior セルロース誘導体の置換基分布,分子内水素結合性,および溶解挙動に関するNMR的研究
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著者
書誌事項
- タイトル
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Nuclear magnetic resonance studies on the substituent group distribution intramolecular hydrogen bond nature in cellulose derivatives and their solubility behavior
- タイトル別名
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セルロース誘導体の置換基分布,分子内水素結合性,および溶解挙動に関するNMR的研究
- 著者名
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上阪, 圭介
- 著者別名
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コウサカ, ケイスケ
- 学位授与大学
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金沢大学
- 取得学位
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学術博士
- 学位授与番号
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乙第1147号
- 学位授与年月日
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1991-03-25
注記・抄録
博士論文
目次
- CONTENTS / (0003.jp2)
- Chapter1.INTRODUCTION / p1 (0006.jp2)
- Purpose and Scope of the Study / p2 (0007.jp2)
- Chapter2.CHARACTERIZATION OF SUBSTITUENT GROUP DISTRIBUTION ON CELLULOSE ACETATE / p24 (0018.jp2)
- 2.1.Determination of the Peak Assignment of Carbonyl Carbon Region in ¹³C{¹H} NMR Spectrum of Cellulose Triacetate / p25 (0018.jp2)
- 2.2.Two-Dimensional Nuclear Magnetic Resonance Spectra of Cellulose and Cellulose Triacetate / p39 (0025.jp2)
- 2.3.Determination of the Distribution of Substituent Group in Cellulose Acetate by Full Assignment of All Carbonyl Carbon Peaks of ¹³C{¹H} NMR Spectra / p58 (0035.jp2)
- 2.4.Determination of Sequence Distribution of Substituted and Unsubstituted Glucopyranose units in Water-Soluble Cellulose Acetate Chain as Revealed by Enzymatic Degradation / p80 (0046.jp2)
- Chapter3.CHARACTERIZATION OF THE SUBSTITUENT GROUP DISTRIBUTION OF VARIOUS CELLULOSE DERIVATIVES / p108 (0060.jp2)
- 3.1.Effect of the Distribution of Substitution of the Sodium Salt of Carboxymethyl Cellulose on its Absorbency toward Aqueous Liquid / p109 (0060.jp2)
- 3.2.Determination of the Distribution of Substituent Groups on Trihydric Alcohol Units in Cellulose Xanthate by ¹³C NMR / p130 (0071.jp2)
- 3.3.Determination of the Distribution of Substituent Groups in Sodium Cellulose Sulfate: Assignment of ¹H and ¹³C Peaks by Two-Dimensional COSY and C-H COSY Methods / p151 (0081.jp2)
- Chapter4.CHARACTERIZATION OF THE SUPER-MOLECULAR STRUCTURE OF CELLULOSE SOLID / p181 (0096.jp2)
- 4.1.Solubility of Regenerated Cellulose in Aqueous Alkali : A Deuteration IR and ¹³C NMR Study / p182 (0097.jp2)
- 4.2.CP/MAS ¹³C NMR Spectra of Cellulose Solids: An Explanation by the Intramolecular Hydrogen Bond Concept / p206 (0109.jp2)
- 4.3.Determination of Intramolecular Hydrogen Bonds and Selective Coordination of Sodium Cation in Alkali Cellulose by CP/MAS ¹³C NMR / p219 (0115.jp2)
- 4.4.Temperature Dependence of Limiting Viscosity Number and Radius of Gyration for Cellulose Dissolved in aq. 8% Sodium Hydroxide Solution / p229 (0120.jp2)
- 4.5.Solubility and Mechanism of Dissolution of Natural Cellulose into Aqueous Alkali: Role of Super-Molecular Structure of Cellulose / p251 (0131.jp2)
- Chapter5.DISTRIBUTION OF SUBSTITUENT GROUPS, SUPER-MOLECULAR STRUCTURE AND SOLUBILITY OF CELLULOSE DERIVATIVES / p280 (0146.jp2)
- 5.1.Solubility of Cellulose Acetate Prepared by Different Methods and its Correlationships with Average Acetyl Group Distribution on Glucopyranose Units / p281 (0146.jp2)
- 5.2.Solvation in Cellulose Triacetate Solution: A Pulse-Fourier ¹H- and ¹³C-NMR Study / p297 (0154.jp2)
- 5.3.Experimental Evidence for Existence of Intramolecular Hydrogen Bond in Water-Insoluble Sodium Salt of Carboxyethyl Cellulose Solid / p311 (0161.jp2)
- 5.4.Tentative Explanation of Solubility Behavior of Cellulose Acetate into Various Solvents in Terms of Super-Molecular Structure Formed by Introduction of Substituent Group in Glucopyranose Unit / p324 (0168.jp2)
- 5.5.Distribution of Substituent Groups of Cellulose Nitrate Obtained by Different Denitration Method and Their Solubility Behavior / p358 (0185.jp2)
- Chapter6.CONCLUSION / p372 (0192.jp2)
- ACKNOWLEDGEMENTS / p382 (0197.jp2)
- List of Publication / p383 (0197.jp2)