Nuclear magnetic resonance studies on the substituent group distribution intramolecular hydrogen bond nature in cellulose derivatives and their solubility behavior セルロース誘導体の置換基分布,分子内水素結合性,および溶解挙動に関するNMR的研究

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著者

    • 上阪, 圭介 コウサカ, ケイスケ

書誌事項

タイトル

Nuclear magnetic resonance studies on the substituent group distribution intramolecular hydrogen bond nature in cellulose derivatives and their solubility behavior

タイトル別名

セルロース誘導体の置換基分布,分子内水素結合性,および溶解挙動に関するNMR的研究

著者名

上阪, 圭介

著者別名

コウサカ, ケイスケ

学位授与大学

金沢大学

取得学位

学術博士

学位授与番号

乙第1147号

学位授与年月日

1991-03-25

注記・抄録

博士論文

目次

  1. CONTENTS / (0003.jp2)
  2. Chapter1.INTRODUCTION / p1 (0006.jp2)
  3. Purpose and Scope of the Study / p2 (0007.jp2)
  4. Chapter2.CHARACTERIZATION OF SUBSTITUENT GROUP DISTRIBUTION ON CELLULOSE ACETATE / p24 (0018.jp2)
  5. 2.1.Determination of the Peak Assignment of Carbonyl Carbon Region in ¹³C{¹H} NMR Spectrum of Cellulose Triacetate / p25 (0018.jp2)
  6. 2.2.Two-Dimensional Nuclear Magnetic Resonance Spectra of Cellulose and Cellulose Triacetate / p39 (0025.jp2)
  7. 2.3.Determination of the Distribution of Substituent Group in Cellulose Acetate by Full Assignment of All Carbonyl Carbon Peaks of ¹³C{¹H} NMR Spectra / p58 (0035.jp2)
  8. 2.4.Determination of Sequence Distribution of Substituted and Unsubstituted Glucopyranose units in Water-Soluble Cellulose Acetate Chain as Revealed by Enzymatic Degradation / p80 (0046.jp2)
  9. Chapter3.CHARACTERIZATION OF THE SUBSTITUENT GROUP DISTRIBUTION OF VARIOUS CELLULOSE DERIVATIVES / p108 (0060.jp2)
  10. 3.1.Effect of the Distribution of Substitution of the Sodium Salt of Carboxymethyl Cellulose on its Absorbency toward Aqueous Liquid / p109 (0060.jp2)
  11. 3.2.Determination of the Distribution of Substituent Groups on Trihydric Alcohol Units in Cellulose Xanthate by ¹³C NMR / p130 (0071.jp2)
  12. 3.3.Determination of the Distribution of Substituent Groups in Sodium Cellulose Sulfate: Assignment of ¹H and ¹³C Peaks by Two-Dimensional COSY and C-H COSY Methods / p151 (0081.jp2)
  13. Chapter4.CHARACTERIZATION OF THE SUPER-MOLECULAR STRUCTURE OF CELLULOSE SOLID / p181 (0096.jp2)
  14. 4.1.Solubility of Regenerated Cellulose in Aqueous Alkali : A Deuteration IR and ¹³C NMR Study / p182 (0097.jp2)
  15. 4.2.CP/MAS ¹³C NMR Spectra of Cellulose Solids: An Explanation by the Intramolecular Hydrogen Bond Concept / p206 (0109.jp2)
  16. 4.3.Determination of Intramolecular Hydrogen Bonds and Selective Coordination of Sodium Cation in Alkali Cellulose by CP/MAS ¹³C NMR / p219 (0115.jp2)
  17. 4.4.Temperature Dependence of Limiting Viscosity Number and Radius of Gyration for Cellulose Dissolved in aq. 8% Sodium Hydroxide Solution / p229 (0120.jp2)
  18. 4.5.Solubility and Mechanism of Dissolution of Natural Cellulose into Aqueous Alkali: Role of Super-Molecular Structure of Cellulose / p251 (0131.jp2)
  19. Chapter5.DISTRIBUTION OF SUBSTITUENT GROUPS, SUPER-MOLECULAR STRUCTURE AND SOLUBILITY OF CELLULOSE DERIVATIVES / p280 (0146.jp2)
  20. 5.1.Solubility of Cellulose Acetate Prepared by Different Methods and its Correlationships with Average Acetyl Group Distribution on Glucopyranose Units / p281 (0146.jp2)
  21. 5.2.Solvation in Cellulose Triacetate Solution: A Pulse-Fourier ¹H- and ¹³C-NMR Study / p297 (0154.jp2)
  22. 5.3.Experimental Evidence for Existence of Intramolecular Hydrogen Bond in Water-Insoluble Sodium Salt of Carboxyethyl Cellulose Solid / p311 (0161.jp2)
  23. 5.4.Tentative Explanation of Solubility Behavior of Cellulose Acetate into Various Solvents in Terms of Super-Molecular Structure Formed by Introduction of Substituent Group in Glucopyranose Unit / p324 (0168.jp2)
  24. 5.5.Distribution of Substituent Groups of Cellulose Nitrate Obtained by Different Denitration Method and Their Solubility Behavior / p358 (0185.jp2)
  25. Chapter6.CONCLUSION / p372 (0192.jp2)
  26. ACKNOWLEDGEMENTS / p382 (0197.jp2)
  27. List of Publication / p383 (0197.jp2)
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各種コード

  • NII論文ID(NAID)
    500000078327
  • NII著者ID(NRID)
    • 8000000078531
  • DOI(NDL)
  • NDL書誌ID
    • 000000242641
  • データ提供元
    • NDL-OPAC
    • NDLデジタルコレクション
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