Study on the asymmetric synthesis of optically active alcohols using organozinc reagents 有機亜鉛試薬を用いる光学活性アルコールの不斉合成に関する研究

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著者

    • 丹羽, 誠司 ニワ, セイジ

書誌事項

タイトル

Study on the asymmetric synthesis of optically active alcohols using organozinc reagents

タイトル別名

有機亜鉛試薬を用いる光学活性アルコールの不斉合成に関する研究

著者名

丹羽, 誠司

著者別名

ニワ, セイジ

学位授与大学

東京理科大学

取得学位

理学博士

学位授与番号

甲第169号

学位授与年月日

1991-03-20

注記・抄録

博士論文

目次

  1. Contents / (0003.jp2)
  2. Introduction / p1 (0006.jp2)
  3. Chapter1. Catalytic Asymmetric Synthesis of Optically Active Alkynyl Alcohols by Enantioselective Alkynylation of Aldehydes and by Enantioselective Alkylation of Alkynyl Aldehydes / p7 (0012.jp2)
  4. I. Introduction / p7 (0012.jp2)
  5. II. Enantioselective Addition of Alkynylzinc Reagents to Aldeydes / p8 (0013.jp2)
  6. III. Enantioselective Addition of Dialkylzincs to Alkynyl Aldehydes / p23 (0028.jp2)
  7. Conclusion / p30 (0035.jp2)
  8. Experimental / p31 (0036.jp2)
  9. References / p36 (0041.jp2)
  10. Chapter2. Polymer-Bound N-Alkylnorephedrines as Efficient Chiral Catalysts for the Enantioselective Addition of Dial-kylzincs to Both Aromatic and Aliphatic Aldehydes / p40 (0045.jp2)
  11. I. Introduction / p40 (0045.jp2)
  12. II. Preparation of Polymer-Bound N-Alkylnorephedrines / p41 (0046.jp2)
  13. III. Enantioselective Addition of Dialkylzincs to Aldehydes Using Polymer-Bound Ephedrine as a Catalyst / p46 (0051.jp2)
  14. IV. Enantioselective Addition of Diethylzinc to Ali-phatic Aldehydes Using Polymer-Bound N-Alkylnorephed-rines / p51 (0056.jp2)
  15. Conclusion / p57 (0062.jp2)
  16. Experimental / p58 (0063.jp2)
  17. References / p62 (0067.jp2)
  18. Chapter3. Asymmetric Synthesis of Alcohols with Two ChiralCenters from a Racemic Aldehyde by the Selective Addition of Dialkylzinc Reagents / p64 (0069.jp2)
  19. I. Introduction / p64 (0069.jp2)
  20. II. Highly Diastereoselective 1,2-Asymmetric Addition of Dialkylzincs to Chiral 2-Phenylpropanal Catalyzed by Amino Alcohol / p65 (0070.jp2)
  21. III. Asymmetric Synthesis of Alcohols with Two Chiral Centers from Racemic Aldehyde by the Selective Addition of Dialkylzincs Using Chiral Catalysts / p70 (0075.jp2)
  22. Conclusion / p79 (0084.jp2)
  23. Experimental / p80 (0085.jp2)
  24. References / p82 (0087.jp2)
  25. Chapter4. Chiral Piperazine as a New Chiral Catalyst for the Enantioselective Addition of Dialkylzincs to Aryl Alde-hydes / p84 (0089.jp2)
  26. I. Introduction / p84 (0089.jp2)
  27. II. Results and Discussions / p85 (0090.jp2)
  28. Conclusion / p95 (0100.jp2)
  29. Experimental / p96 (0101.jp2)
  30. References / p99 (0104.jp2)
  31. Chapter5. Enantioselective Addition of Dialkylzincs to Pyridinecarbaldehyde and Asymmetric Self-Catalytic Reaction. / p101 (0106.jp2)
  32. I. Introduction / p101 (0106.jp2)
  33. II. Enantioselective Addition of Dialkylzincs to Pyri-dinecarbaldehyde in the Presence of Chiral Amino Alco-hols / p102 (0107.jp2)
  34. III. Asymmetric Self-Catalytic Reaction.Self-produc-tion of Chiral 3-Pyridylalkylalcohols as Chiral Self-Catalysts in the Enantioselective Addition of Dialkyl-zinc Reagents to 3-Pyridinecarbaldehyde / p108 (0113.jp2)
  35. Conclusion / p112 (0117.jp2)
  36. Experimental / p113 (0118.jp2)
  37. References / p116 (0121.jp2)
  38. Conclusion / p118 (0123.jp2)
  39. Ackowledgement / p120 (0125.jp2)
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各種コード

  • NII論文ID(NAID)
    500000079175
  • NII著者ID(NRID)
    • 8000000079379
  • DOI(NDL)
  • NDL書誌ID
    • 000000243489
  • データ提供元
    • NDL ONLINE
    • NDLデジタルコレクション

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