Syntheses and magnetic properties of conjugated polymers possessing stable nitroxide radicals 安定ニトロキシドラジカルを有する共役ポリマーの合成と磁気的性質

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著者

    • 石田, 尚行 イシダ, タカユキ

書誌事項

タイトル

Syntheses and magnetic properties of conjugated polymers possessing stable nitroxide radicals

タイトル別名

安定ニトロキシドラジカルを有する共役ポリマーの合成と磁気的性質

著者名

石田, 尚行

著者別名

イシダ, タカユキ

学位授与大学

東京大学

取得学位

理学博士

学位授与番号

甲第8909号

学位授与年月日

1991-03-29

注記・抄録

博士論文

目次

  1. Contents / (0004.jp2)
  2. Chapter1.General Introduction / p1 (0007.jp2)
  3. 1.1.Organic Ferromagnets / p1 (0007.jp2)
  4. 1.2.Scope of This Thesis / p4 (0010.jp2)
  5. 1.3.Molecular Design / p6 (0012.jp2)
  6. References / p11 (0017.jp2)
  7. Chapter2.Magnetic Measurements / p16 (0022.jp2)
  8. 2.1.Theoretical Treatment / p16 (0022.jp2)
  9. 2.2.Interpretation of Magnetic Phenomena / p20 (0026.jp2)
  10. 2.3.Magnetic Measurements / p22 (0028.jp2)
  11. 2.4.Analyses of Magnetic Data / p24 (0030.jp2)
  12. References / p25 (0031.jp2)
  13. Chapter3.Bis[3-t-butyl-5-(N-oxy-t-butylamino)phenyl]Nitroxide in a Quartet Ground State / p26 (0032.jp2)
  14. 3.1.Introduction / p26 (0032.jp2)
  15. 3.2.Synthesis / p27 (0033.jp2)
  16. 3.3.ESR spectra / p28 (0034.jp2)
  17. 3.4.Magnetic Properties / p31 (0037.jp2)
  18. 3.5.Magnetic Properties of m-Phenylene Bis(t-butyl Nitroxide)Biradical / p34 (0040.jp2)
  19. 3.6.Ground State High Spin Molecules / p34 (0040.jp2)
  20. 3.7.Summary / p35 (0041.jp2)
  21. Experimental / p36 (0042.jp2)
  22. References / p39 (0045.jp2)
  23. Chapter4.Poly(oxyimino-1,3-phenylenes) / p41 (0047.jp2)
  24. 4.1.Introduction / p41 (0047.jp2)
  25. 4.2.Synthesis via m-Di1itiobenzene / p42 (0048.jp2)
  26. 4.3.ESR Broad Signal / p44 (0050.jp2)
  27. 4.4.Saturated Magnetization Curves / p46 (0052.jp2)
  28. 4.5.A Possible Structure / p48 (0054.jp2)
  29. 4.6.Poly(oxyimino-5-t-butyl-l,3-phenylene) / p50 (0056.jp2)
  30. 4.7.Summary / p52 (0058.jp2)
  31. Experimental / p53 (0059.jp2)
  32. References / p55 (0061.jp2)
  33. Chapter5.Synthesis of Poly(m-aniline) and Magnetic Properties of the Oxidized Product / p56 (0062.jp2)
  34. 5.1.Introduction / p56 (0062.jp2)
  35. 5.2.Synthesis of Poly(m-aniline) / p57 (0063.jp2)
  36. 5.3.Properties of Poly(m-aniline) / p58 (0064.jp2)
  37. 5.4.Synthesis and Magnetic Properties of Its Oxidized Product / p58 (0064.jp2)
  38. 5.5.Synthesis and Magnetic Properties of Its HCl Salt / p61 (0067.jp2)
  39. 5.6.Summary / p63 (0069.jp2)
  40. Experimental / p63 (0069.jp2)
  41. References / p65 (0071.jp2)
  42. Chapter6.Poly(phenylacetylenes)Carrying Nitroxide Radicals on the Phenyl Ring(I) / p66 (0072.jp2)
  43. 6.1.Introduction / p66 (0072.jp2)
  44. 6.2.Polymerization / p67 (0073.jp2)
  45. 6.3.Synthesis of Polynitroxides / p74 (0080.jp2)
  46. 6.4.ESR Spectra / p74 (0080.jp2)
  47. 6.5.Paramagnetic Properties / p76 (0082.jp2)
  48. 6.6.Interpretation of the Magnetism / p78 (0084.jp2)
  49. 6.7.Summary / p79 (0085.jp2)
  50. Experimental / p79 (0085.jp2)
  51. References / p90 (0096.jp2)
  52. Chapter7.Poly(phenylacetylenes)Carrying Nitroxide Radicals on the Phenyl Ring(II) / p92 (0098.jp2)
  53. 7.1.Introduction / p92 (0098.jp2)
  54. 7.2.Synthesis via Polybromide / p93 (0099.jp2)
  55. 7.3.ESR Spectra / p95 (0101.jp2)
  56. 7.4.Paramagnetic Properties / p96 (0102.jp2)
  57. 7.5.Interpretation of the Magnetism / p99 (0105.jp2)
  58. 7.6.Cross-linked Polymers / p101 (0107.jp2)
  59. 7.7.Summary / p103 (0109.jp2)
  60. Experimental / p104 (0110.jp2)
  61. References / p107 (0113.jp2)
  62. Chapter8.1,1-Bis[3-(N-oxy-t-butylamino)phenyl]ethylene:a Disjoint Biradical / p109 (0115.jp2)
  63. 8.1.Introduction / p109 (0115.jp2)
  64. 8.2.Synthesis / p111 (0117.jp2)
  65. 8.3.Magnetic Properties / p112 (0118.jp2)
  66. 8.4.Disjoint Nondisjoint Classification / p114 (0120.jp2)
  67. 8.5.Interaction through a sp³ Carbon Atom / p115 (0121.jp2)
  68. 8.6.Summary / p117 (0123.jp2)
  69. Experimental / p117 (0123.jp2)
  70. References / p121 (0127.jp2)
  71. Chapter9.Concluding Remarks / p122 (0128.jp2)
  72. Experimental / p125 (0131.jp2)
  73. References / p129 (0135.jp2)
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各種コード

  • NII論文ID(NAID)
    500000081667
  • NII著者ID(NRID)
    • 8000000081875
  • DOI(NDL)
  • NDL書誌ID
    • 000000245981
  • データ提供元
    • NDL-OPAC
    • NDLデジタルコレクション
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