Reaction of α-aminomalonate with Co(Ⅲ)-polyamine complexes involving electron transfer 電子移動を伴うα-アミノマロン酸とコバルト(Ⅲ)-ポリアミン錯体との反応

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著者

    • 小島, 隆彦 コジマ, タカヒコ

書誌事項

タイトル

Reaction of α-aminomalonate with Co(Ⅲ)-polyamine complexes involving electron transfer

タイトル別名

電子移動を伴うα-アミノマロン酸とコバルト(Ⅲ)-ポリアミン錯体との反応

著者名

小島, 隆彦

著者別名

コジマ, タカヒコ

学位授与大学

東京大学

取得学位

工学博士

学位授与番号

甲第9053号

学位授与年月日

1991-03-29

注記・抄録

博士論文

目次

  1. List of Contents / (0003.jp2)
  2. Preface / (0006.jp2)
  3. Chapter1. / (0007.jp2)
  4. General Introduction / 1-1 / (0008.jp2)
  5. References / 1-15 / (0022.jp2)
  6. Polyamine Systems Discussed in This Thesis / 1-22 / (0029.jp2)
  7. Chapter2 Synthesis and Characterization of Cobalt(III) Complexes Containing α-Diamine and Carbinolamine Derived from α-Aminomalonate and Ethylenediamine / (0030.jp2)
  8. Introduction / 2-2 / (0032.jp2)
  9. Experimental Section / 2-5 / (0035.jp2)
  10. Results / 2-11 / (0041.jp2)
  11. Discussion / 2-22 / (0052.jp2)
  12. Summary / 2-23 / (0053.jp2)
  13. References and Notes / 2-25 / (0055.jp2)
  14. Chapter3 Syntheses and Characterization of Complexes Derived from α-Aminomalonate and trans-〔CoCl₂(3,7-diaza-1,9-diaminononane)〕⁺ / (0057.jp2)
  15. Introduction / 3-2 / (0059.jp2)
  16. Experimental Section / 3-5 / (0062.jp2)
  17. Results / 3-26 / (0083.jp2)
  18. Discussion / 3-41 / (0098.jp2)
  19. Summary / 3-46 / (0103.jp2)
  20. References and Notes / 3-47 / (0104.jp2)
  21. Chapter4 Concerted Regulation of Intermolecular C-N Bond Formation of α-Aminomalonate with trans-〔CoCl₂(4,7-diaza-1,10-diaminodecane)〕⁺ By Counter Anion and Dioxygen. / (0107.jp2)
  22. Introduction / 4-2 / (0109.jp2)
  23. Experimental / 4-2 / (0109.jp2)
  24. Results and Discussion / 4-10 / (0117.jp2)
  25. References and Notes / 4-17 / (0124.jp2)
  26. Chapter5 Unprecedented Imido-Bridged Binuclear Cobalt(III) Complex: Synthesis and Molecular Structure of p-〔Co₂(μ-(μ₂-N:η¹-O,O¹)-Imidomalonato)(tren)₂〕(ClO₄)₃・H2O. / (0126.jp2)
  27. Introduction / 5-2 / (0128.jp2)
  28. Experimental Section / 5-2 / (0128.jp2)
  29. Results and Discussion / 5-6 / (0132.jp2)
  30. References and Notes / 5-16 / (0142.jp2)
  31. Chapter6 Photoinductive Oxidative Decarboxylation of α-Aminomalonate on Co(III)-Polyamine Complexes: Formation of Oxamato and Oxalato Complexes. / (0144.jp2)
  32. Introduction / 6-1 / (0145.jp2)
  33. Experimental Section / 6-3 / (0147.jp2)
  34. Results and Discussion / 6-10 / (0154.jp2)
  35. References and Notes / 6-15 / (0159.jp2)
  36. Chapter7 Observation of Radical Intermediates for Unusual C-N Bond Formation of α-Aminomalonate to Give α-Diamine Linkage. ESR Studies on Electron Transfer Reactions in Co(III)-Polyamine Complexes. / (0161.jp2)
  37. Introduction / 7-2 / (0163.jp2)
  38. Experimental Section / 7-4 / (0165.jp2)
  39. Results and Discussion / 7-6 / (0167.jp2)
  40. Summary / 7-35 / (0196.jp2)
  41. References and Notes / 7-38 / (0199.jp2)
  42. List of Publications / (0205.jp2)
  43. Acknowledgment / (0208.jp2)
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各種コード

  • NII論文ID(NAID)
    500000081811
  • NII著者ID(NRID)
    • 8000000082019
  • DOI(NDL)
  • NDL書誌ID
    • 000000246125
  • データ提供元
    • NDL-OPAC
    • NDLデジタルコレクション
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