Strategies for asymmetric cyclization based on conjugate addition 共役付加に基づく不斉環化反応の研究
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著者
書誌事項
- タイトル
-
Strategies for asymmetric cyclization based on conjugate addition
- タイトル別名
-
共役付加に基づく不斉環化反応の研究
- 著者名
-
方, 成林
- 著者別名
-
ファン, チェンリン
- 学位授与大学
-
九州大学
- 取得学位
-
薬学博士
- 学位授与番号
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乙第4976号
- 学位授与年月日
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1991-07-17
注記・抄録
博士論文
目次
- CONTENTS / p4 (0004.jp2)
- INTRODUCTION / p1 (0005.jp2)
- LIST OF PUBLICATIONS / p5 (0007.jp2)
- CHAPTER I A Novel Stereocontrolled Cyclization and Its Application to Synthesis of 11-Deoxy PGE₁ / p6 (0008.jp2)
- 1. General Consideration / p6 (0008.jp2)
- 2. Stereocontrolled Formation of Trisubstituted Five-and Six-Membered Ring / p9 (0009.jp2)
- 3. Establishment of a New Synthetic Route of 11-Deoxy PGE₁ / p14 (0012.jp2)
- 4. Discussion / p17 (0013.jp2)
- CHAPTER II One-pot Construction of Oxapropellane Skeleton / p20 (0015.jp2)
- 1. General Aspect / p20 (0015.jp2)
- 2. One-pot Construction of Oxapropellane Skeleton / p21 (0015.jp2)
- 3. Attempt of One-pot Construction of Other Tricyclic Compound / p32 (0021.jp2)
- 4. Conclusion / p35 (0022.jp2)
- CHAPTER III Diastereoselective Conjugate Addition / p36 (0023.jp2)
- 1. Introduction / p36 (0023.jp2)
- 2. Diastereoselective Conjugate Addition / p38 (0024.jp2)
- 3. Proposed Mechanism / p45 (0027.jp2)
- CHAPTER IV Asymmetric Cyclization Based on Asymmetric Conjugate Addition and Intramolecular Trapping of the Enolate. / p52 (0031.jp2)
- 1. General Aspect / p52 (0031.jp2)
- 2. Synthesis of 1,2-Disubstituted Chiral Cyclopentanes and Cyclohexanes / p53 (0031.jp2)
- 3. Synthesis of Muscone Based on Conjugate Addition and Intramolecular Acylation of the Enolate. / p69 (0039.jp2)
- SUMMARY OF THE ORIGINAL WORKS / p74 (0042.jp2)
- EXPERIMENTAL SECTION / p76 (0043.jp2)
- CHAPTER I / p77 (0043.jp2)
- CHAPTER II / p81 (0045.jp2)
- CHAPTER III / p90 (0050.jp2)
- CHAPTER IV / p94 (0052.jp2)
- REFERENCES AND NOTES / p102 (0056.jp2)
