Dynamic study of hydrogen-ion strength of solid state organic materials and applications : use of hydrogen-isotope exchange in a heterogeneous system 固体有機化合物の水素イオン強度の動的研究とその応用 : 不均一系での水素同位体交換の利用

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著者

    • 今泉, 洋 イマイズミ, ヒロシ

書誌事項

タイトル

Dynamic study of hydrogen-ion strength of solid state organic materials and applications : use of hydrogen-isotope exchange in a heterogeneous system

タイトル別名

固体有機化合物の水素イオン強度の動的研究とその応用 : 不均一系での水素同位体交換の利用

著者名

今泉, 洋

著者別名

イマイズミ, ヒロシ

学位授与大学

東京大学

取得学位

工学博士

学位授与番号

乙第9797号

学位授与年月日

1990-07-12

注記・抄録

博士論文

目次

  1. CONTENTS / p2 (0004.jp2)
  2. Chapter1 Introduction / p1 (0010.jp2)
  3. 1.1 Situation of this work / p1 (0010.jp2)
  4. 1.2 Purpose of this work / p11 (0020.jp2)
  5. 1.3 Sample marerials used / p12 (0021.jp2)
  6. 1.4 Structure of this report / p13 (0022.jp2)
  7. Chapter2 Theory / p16 (0025.jp2)
  8. 2.1 Isotope exhange reaction and isotope effect / p16 (0025.jp2)
  9. 2.2 Mckay's equation / p18 (0027.jp2)
  10. 2.3 Concept of A" / p19 (0028.jp2)
  11. 2.4 A"-McKay plot / p22 (0031.jp2)
  12. 2.5“Hydrogen-ion strength”of materials and“acidty based on kinetic logic”for materials / p25 (0034.jp2)
  13. 2.6 Necessity of correction for A"-McKay plot / p27 (0036.jp2)
  14. 2.7 Limitation of the use of A"-McKay plot / p29 (0038.jp2)
  15. 2.8 Effect of β-ray emitted from ³H atoms on the exchange reaction / p31 (0040.jp2)
  16. Chapter3 Experimental / p32 (0041.jp2)
  17. 3.1 Sample materials / p32 (0041.jp2)
  18. 3.2 Gas-solid reaction / p34 (0043.jp2)
  19. 3.3 Liquid-solid reaction / p39 (0048.jp2)
  20. 3.4 The other experiments / p41 (0050.jp2)
  21. Chapter4 Method of measurment of“hydrogen-ion strength”of materials / p45 (0054.jp2)
  22. 4.1 Comparison of McKay plot with A"-McKay plot / p45 (0054.jp2)
  23. 4.2 Validity for applying A"-McKay plot / p53 (0062.jp2)
  24. Chapter5 Application of the concept of“hydrogen-ion strength”of materials to solid compounds / p68 (0077.jp2)
  25. 5.1 Comparison of“the acidity based on kinetic logic”of various species of monohydrogenphosphates / p68 (0077.jp2)
  26. 5.2“Acidities based on kinetic logic”of amines / p80 (0089.jp2)
  27. 5.3 Comparison of phthalic acids(o-,m-,and p-)with each other in reactivity / p88 (0097.jp2)
  28. 5.4“Acidities based on kinetic logic”of monosubstituted benzoic acids / p96 (0105.jp2)
  29. Chapter6 Application of the concept of“hydrogen-ion strength”of materials to solid compounds / p111 (0120.jp2)
  30. 6.1 Comparison of a gas-solid reaction with a liquid-solid reaction / p111 (0120.jp2)
  31. 6.2“Acidity based on kinetic logic”of alcohols and that of carboxylic acids / p118 (0127.jp2)
  32. 6.3“Acidities based on kinetic logic”of monosubstituted benzaldehydes / p134 (0143.jp2)
  33. 6.4“Acidity based on kinetic logic”of monosubstituted anilines / p147 (0156.jp2)
  34. Chapter7 Conclusion / p158 (0167.jp2)
  35. Acknowledgements / p162 (0171.jp2)
  36. References / p163 (0172.jp2)
  37. List of publications / p171 (0180.jp2)
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各種コード

  • NII論文ID(NAID)
    500000083124
  • NII著者ID(NRID)
    • 8000000083334
  • DOI(NDL)
  • NDL書誌ID
    • 000000247438
  • データ提供元
    • NDL-OPAC
    • NDLデジタルコレクション
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