Systematic studies on the mixed-valence states of perovskite-type transition-metal complexes Cs[2]Au[2]X[6] (X=Cl, Br, I) ペロブスカイト型遷移金属錯体Cs[2]Au[2]X[6](X=Cl,Br,I)の混合原子価状態に関する系統的研究

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著者

    • 北川, 宏 キタガワ, ヒロシ

書誌事項

タイトル

Systematic studies on the mixed-valence states of perovskite-type transition-metal complexes Cs[2]Au[2]X[6] (X=Cl, Br, I)

タイトル別名

ペロブスカイト型遷移金属錯体Cs[2]Au[2]X[6](X=Cl,Br,I)の混合原子価状態に関する系統的研究

著者名

北川, 宏

著者別名

キタガワ, ヒロシ

学位授与大学

京都大学

取得学位

理学博士

学位授与番号

甲第4980号

学位授与年月日

1992-03-23

注記・抄録

博士論文

目次

  1. 論文目録 / (0001.jp2)
  2. Contents / (0007.jp2)
  3. Chapter1.General Introduction / p1 (0013.jp2)
  4. References / p13 (0025.jp2)
  5. Chapter2.Structure Discussion of Cs₂Au₂X₆(X=Cl,Br,I)and the Mixed-Valence State of CsAu₀.₆Br₂.₆ / p15 (0028.jp2)
  6. 2-1 Introduction / p15 (0028.jp2)
  7. 2-2 Experimental / p16 (0029.jp2)
  8. 2-3 Crystal Structure and Its Anisotropy of Cs₂Au₂X₆ / p18 (0031.jp2)
  9. 2-4 Powder X-Ray Diffraction Profiles of Cs-Au-Br Mixed-Valence System / p24 (0037.jp2)
  10. 2-5 ESR Spectra of the Cubic Phase / p29 (0042.jp2)
  11. 2-6 Electrical Conductivity of the Cubic Phase / p32 (0045.jp2)
  12. 2-7 Conclusions / p33 (0046.jp2)
  13. References / p35 (0048.jp2)
  14. Chapter3.X-Ray Photoelectron Spectroscopic Study of the Mixed-Valence States in Cs₂Au₂X₆(X=Cl,Br,I) / p37 (0051.jp2)
  15. 3-1 Introduction / p37 (0051.jp2)
  16. 3-2 Experimental / p38 (0052.jp2)
  17. 3-3 XPS Spectra of Mixed-Valence Compounds Cs₂Au₂X₆ / p41 (0055.jp2)
  18. 3-4 XPS Spectra of [化学式] Halogeno Complexes / p50 (0064.jp2)
  19. 3-5 XPS Spectra of [化学式] Halogeno Complexes / p52 (0066.jp2)
  20. 3-6 XPS Spectrum of the Cubic Phase CsAu₀.₆Br₂.₆ / p54 (0068.jp2)
  21. 3-7 Conclusions / p55 (0069.jp2)
  22. References / p56 (0070.jp2)
  23. Chapter4.Gold-197 Mössbauer Spectroscopic Study of the Mixed-Valence States in Cs₂Au₂X₆ (X=C1,Br,I) / p59 (0074.jp2)
  24. 4-1 Introduction / p59 (0074.jp2)
  25. 4-2 Experimental / p60 (0075.jp2)
  26. 4-3 Difference in Recoil-Free Fractions for the [化学式] and [化学式] sites in Cs₂Au₂X₆ / p61 (0076.jp2)
  27. 4-4 Mössbauer Spectra of Cs₂Au₂X₆ / p65 (0080.jp2)
  28. 4-5 Quadrupole Splitting of [化学式] in Cs₂Au₂X₆ / p69 (0084.jp2)
  29. 4-6 Quadrupole Splitting of [化学式] in Cs₂Au₂X₆ / p73 (0088.jp2)
  30. 4-7 Isomer Shifts of [化学式] and [化学式] in Cs₂Au₂X₆ / p76 (0091.jp2)
  31. 4-8 Mössbauer Spectrum of the Cubic Phase CsAu₀.₆Br₂.₆ / p78 (0093.jp2)
  32. 4-9 Conclusions / p80 (0095.jp2)
  33. References / p81 (0096.jp2)
  34. Chapter5.Intervalence Charge-Transfer Absorption / p84 (0100.jp2)
  35. 5-1 Introduction / p84 (0100.jp2)
  36. 5-2 History of Intervalence Charge-Transfer Absorption in Related Compounds / p85 (0101.jp2)
  37. 5-3 Questions in Previous Optical Studies for Wells Salt / p93 (0109.jp2)
  38. 5-4 Experimental / p96 (0112.jp2)
  39. 5-5 Intervalence Charge-Transfer Absorption Spectra of Cs₂Au₂X₆ / p97 (0113.jp2)
  40. 5-6 Single-Crystal Polarized Reflectance Spectra of Cs₂Au₂I₆ / p102 (0118.jp2)
  41. 5-7 Return to the Problems / p106 (0122.jp2)
  42. 5-8 Conelusions / p109 (0125.jp2)
  43. References / p110 (0126.jp2)
  44. Chapter6.Behavior of the Electrical Conductivity of the Three-Dimensional Mixed-Valence Compounds Cs₂Au₂X₆(X=Cl,Br,I)under High Pressure / p111 (0128.jp2)
  45. 6-1 Introduction / p111 (0128.jp2)
  46. 6-2 Experimental / p112 (0129.jp2)
  47. 6-3 Behavior of Electrical Resistivity under High Pressure / p114 (0131.jp2)
  48. 6-4 Behavior of Energy Gap under High Pressure / p118 (0135.jp2)
  49. 6-5 Metal-to-Metal Transition of Cs₂Au₂I₆ / p124 (0141.jp2)
  50. 6-6 Conclusions / p127 (0144.jp2)
  51. References / p128 (0145.jp2)
  52. Chapter7.Consecutive Phase Transitions of the 3-D Mixed-Valence Complex Cs₂Au₂I₆ under High Pressure / p129 (0147.jp2)
  53. 7-1 Introduction / p129 (0147.jp2)
  54. 7-2 Experimental / p133 (0151.jp2)
  55. 7-3 Pressure Dependence of the Lattice Constants / p134 (0152.jp2)
  56. 7-4 Pressure-Induced Jahn-Teller Transformation at 5.5 GPa / p137 (0155.jp2)
  57. 7-5 Realization of a Rare Gold-II Valence State under High Pressure / p139 (0157.jp2)
  58. 7-6 Cubic Phase and Metastable Phase / p143 (0161.jp2)
  59. 7-7 Inconsistencies between High-Pressure Studies of Cs₂Au₂I₆ / p148 (0166.jp2)
  60. 7-8 Conclusions / p151 (0169.jp2)
  61. References / p153 (0171.jp2)
  62. Chapter8.Electrical Conductivity and Its Anisotropy of Single Crystal Cs₂Au₂I₆ under High Pressures and Low Temperatures / p155 (0174.jp2)
  63. 8-1 Introductions / p155 (0174.jp2)
  64. 8-2 Experimental / p157 (0176.jp2)
  65. 8-3 Pressure Dependence of the Resistivity at Room Temperature / p161 (0180.jp2)
  66. 8-4 Temperature Dependence of Electrical Resistivity below 5.5 GPa / p164 (0183.jp2)
  67. 8-5 Temperature Dependence of Electrical Resistivity above 5.5 GPa / p172 (0191.jp2)
  68. 8-6 Conclusions / p176 (0195.jp2)
  69. References / p177 (0196.jp2)
  70. Chapter9.General Conclusions / p178 (0198.jp2)
  71. STUDY OF MIXED VALENT STATE IN Cs₂Au₂X₆(X=Cl,Br and I) / (0218.jp2)
  72. STRUCTURE ANALYSIS OF HIGH-PRESSURE METALLIC STATE OF THE THREE-DIMENSIONAL MIXED-VALENCE COMPOUND[化学式] BY X-RAY DIFFRACTION USING SR / p1953 (0219.jp2)
  73. BEHAVIOUR OF THE ELECTRICAL CONDUCTIVITY OF THE THREE-DIMENSIONAL MIXED-VALENCE COMPOUNDS Cs₂Au₂X₆(X=Cl,Br,I)UNDER HIGH PRESSURES / p2347 (0221.jp2)
  74. STRUCTURAL PHASE TRANSITIONS AND METALLIZATION IN THE THREE-DIMENSIONAL MIXED-VALENCE COMPOUNDS Cs₂Au₂X₆(X=Cl,Br,I)UNDER HIGH PRESSURE / (0223.jp2)
  75. ペロブスカイト型混合原子価錯体CsAuI₃の圧力誘起相転移 / p1 (0225.jp2)
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各種コード

  • NII論文ID(NAID)
    500000085848
  • NII著者ID(NRID)
    • 8000000086062
  • DOI(NDL)
  • NDL書誌ID
    • 000000250162
  • データ提供元
    • NDL-OPAC
    • NDLデジタルコレクション
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