Structural studies on novel early transition metal complexes with active organic substrates 活性有機基質の前周期遷移金属錯体に関する構造化学的研究
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Bibliographic Information
- Title
-
Structural studies on novel early transition metal complexes with active organic substrates
- Other Title
-
活性有機基質の前周期遷移金属錯体に関する構造化学的研究
- Author
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金久, 展子
- Author(Another name)
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カネヒサ, ノブコ
- University
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大阪大学
- Types of degree
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工学博士
- Grant ID
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乙第5696号
- Degree year
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1992-04-01
Note and Description
博士論文
Table of Contents
- Contents / (0003.jp2)
- Introduction / p1 (0005.jp2)
- Chapter1.Unique Coordination Geometry of 1,3-Dienes in Early Transition Metal Complexes / p2 (0006.jp2)
- 1-1.X-Ray Evidence for a Mononuclear s-trans-η⁴-1,3-Diene Complex / p3 (0006.jp2)
- 1-2.Unique Bonding and Geometry in η⁵-Cyclopentadienyl-tantalum-Diene Complexes / p17 (0013.jp2)
- 1-3.Molecular Structure of Novel Mono-and Bis(diene) Complexes of Niobium / p46 (0028.jp2)
- References / p61 (0035.jp2)
- Chapter2.Diverse Reaction Courses in the Controlled Carbometallation of Heterocumulenes,Ketones,and Alkyne with Zirconium-Diene Complexes / p64 (0037.jp2)
- 2-1.Molecular Structures of Carbon Dioxide,Isocyanate,and Ketene 1:1 and 1:2 Inserted Compounds / p64 (0037.jp2)
- 2-2.Regio-and Stereoselective Courses for Insertion of Ketones into s-cis-and s-trans-Diene Complexes of Zirconium Leading to(Z)-l,2-Oxazircona-cyclohept-4-enes / p83 (0046.jp2)
- 2-3.Unique Structure of (η⁵-C₅H₅)₂Zr-(CH₂C(CH₃)CHCH₂-C(CH₃)C(CH₃)) Prepared by Regioselective Insertion of 2-Butyne to Zr(η⁵-C₅H₅)₂(Isoprene) / p100 (0055.jp2)
- References / p107 (0058.jp2)
- Chapter3.Versatile Bonding Character of Bulky Phenoxy Ligands in Early Transition Metal Complexes / p110 (0060.jp2)
- 3-1.Stereochemistry of Monophenoxide with Groups4 and 5 Early Transition Metals / p113 (0061.jp2)
- 3-2.Stereochemistry of Bisphenoxide with Groups4 and 5 Early Transition Metals / p121 (0065.jp2)
- 3-3.Versatile Bonding Character of Tungsten Phenoxides / p136 (0073.jp2)
- References / p150 (0080.jp2)
- Concluding Remarks / p152 (0081.jp2)
- List of Publications / p154 (0082.jp2)
- Acknowledgement / p158 (0084.jp2)
