Photocrosslinking of polymers containing cationically polymerizable moieties initiated by sulfonium salts スルホニウム塩によるカチオン重合可能な機能団をもつ高分子の高架橋反応
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著者
書誌事項
- タイトル
-
Photocrosslinking of polymers containing cationically polymerizable moieties initiated by sulfonium salts
- タイトル別名
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スルホニウム塩によるカチオン重合可能な機能団をもつ高分子の高架橋反応
- 著者名
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林, 茂蓬
- 著者別名
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リン, マオポン
- 学位授与大学
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東京工業大学
- 取得学位
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工学博士
- 学位授与番号
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甲第2384号
- 学位授与年月日
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1991-09-30
注記・抄録
博士論文
目次
- 論文目録 / (0002.jp2)
- Chapter1 Introduction / p1 (0006.jp2)
- 1.1 History of photopolymers / p1 (0006.jp2)
- 1.2 Synthetic photopolymers / p3 (0008.jp2)
- 1.3 Photoresists / p5 (0010.jp2)
- 1.4 Photochemistry of crosslinking / p7 (0012.jp2)
- 1.5 Photoinduced cationic polymerization / p8 (0013.jp2)
- 1.6 Scope of the present thesis / p12 (0017.jp2)
- References / p14 (0019.jp2)
- Chapter2 Formation of Benzyl Cation from Benzylsulfonium Salt / p16 (0021.jp2)
- 2.1 Introduction / p16 (0021.jp2)
- 2.2 Observation of benzyl cation by time-resolved absorption spectroscopy / p18 (0023.jp2)
- 2.3 Experimental / p29 (0034.jp2)
- References / p35 (0040.jp2)
- Chapter3 Photocrosslinking of Copolymer of Ethylene-Glycidyl Methacrylate Carrying Epoxy Functions Initiated by Benzylsulfonium Salt / p36 (0041.jp2)
- 3.1 Introduction / p36 (0041.jp2)
- 3.2 Preparation of sample films of copolymer of ethylene-glycidyl methacrylate / p37 (0042.jp2)
- 3.3 Behaviors of benzylsulfonium salt on photoirradiation / p39 (0044.jp2)
- 3.4 Evaluation of photocrosslinking / p42 (0047.jp2)
- 3.5 Plausible mechanism of photocrosslinking of copolymer of ethylene-glycidyl methacrylate / p51 (0056.jp2)
- 3.6 Experimental / p54 (0059.jp2)
- References / p57 (0062.jp2)
- Chapter4 Photocrosslinking of Poly(2,2-Dimethyl-1,3-Dioxolane-4-Methyl Methacrylate)and Copolymers with Methyl Metha-crylate Carrying Cyclic Ketal Functions Initiated by Benzylsulfonium Salt / p58 (0063.jp2)
- 4.1 Introduction / p58 (0063.jp2)
- 4.2 Synthesis of poly(2,2-dimethyl-1,3-dioxolane-4-methyl methacrylate)and copolymers with methyl methacrylate / p60 (0065.jp2)
- 4.3 Photocrosslinking behaviors of poly(2,2-dimethyl-1,3-dioxolane-methyl methacrylate) and copolymers with methyl methacrylate / p63 (0068.jp2)
- 4.4 Experimental / p78 (0083.jp2)
- References / p81 (0086.jp2)
- Chapter5 Photocrosslinking of Copolymers of Vinyloxyethyl Methacrylate-Styrene Carrying Vinylether Function Initiated by Sulfonium Salts / p82 (0087.jp2)
- 5.1 Introduction / p82 (0087.jp2)
- 5.2 Synthesis of copolymers of vinyloxyethyl methacrylate-styrene / p83 (0088.jp2)
- 5.3 Photocrosslinking behaviors of copolymers of vinyloxyethyl methacrylate-styrene / p85 (0090.jp2)
- 5.4 Comparison in photocrosslinking behaviors of copolymers of vinyloxyethyl methacrylate-styrene with copolymers of glycidyl methacrylate-styrene / p103 (0108.jp2)
- 5.5 Experimental / p107 (0112.jp2)
- References / p109 (0114.jp2)
- Chapter6 Summary and Prospects / p110 (0115.jp2)
- List of Publications / p113 (0118.jp2)
- Acknowledgments / p116 (0121.jp2)