A new mechanism of the generation of electron spin polarization through interactions between radical and excited molecule ラジカルと励起分子の相互作用による新しい電子スピン分極発生機構
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Bibliographic Information
- Title
-
A new mechanism of the generation of electron spin polarization through interactions between radical and excited molecule
- Other Title
-
ラジカルと励起分子の相互作用による新しい電子スピン分極発生機構
- Author
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河合, 明雄
- Author(Another name)
-
カワイ, アキオ
- University
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東京工業大学
- Types of degree
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理学博士
- Grant ID
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甲第2396号
- Degree year
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1992-03-26
Note and Description
博士論文
Table of Contents
- 論文目録 / (0002.jp2)
- CONTENTS / p1 (0004.jp2)
- Contents / p1 (0004.jp2)
- List of Figures / p4 (0007.jp2)
- Chapter I Overview of the "SPIN CHEMISTRY" / p1 (0012.jp2)
- 1-1 Contribution of Magnetic Resonance Technique to Photochemistry / p1 (0012.jp2)
- 1-2 Conventional Sources of Electron Spin Polarization / p3 (0014.jp2)
- 1-3 Recent Trends in Spin Chemistry / p11 (0022.jp2)
- 1-4 New Mechanism of the CIDEP Generation / p14 (0025.jp2)
- References / p17 (0028.jp2)
- Chapter II Experimental / p19 (0030.jp2)
- 2-1 Apparatus / p19 (0030.jp2)
- 2-2 Analysis of Time Resolved ESR Signals / p20 (0031.jp2)
- References / p27 (0038.jp2)
- Chapter III Electron Spin Polarization in Radical-Triplet Molecule Systems / p28 (0039.jp2)
- 3-1 Introduction / p28 (0039.jp2)
- 3-2 Experimental / p30 (0041.jp2)
- 3-3 Discovery of New CIDEP Generations / p31 (0042.jp2)
- 3-4 Theory of Radical Triplet Pair Mechanism (RTPM) / p39 (0050.jp2)
- 3-5 Solvent Effects on Net and Multiplet Polarization / p63 (0074.jp2)
- References / p72 (0083.jp2)
- Chapter IV Electron Spin Polarization in Radical-Excited Singlet Molecule Systems / p74 (0085.jp2)
- 4-1 Introduction / p74 (0085.jp2)
- 4-2 Experimental / p76 (0087.jp2)
- 4-3 Net Absorptive and Absorption/Emission (A/E) Multiplet Polarization / p77 (0088.jp2)
- 4-4 RTPM with Doublet Precursor / p81 (0092.jp2)
- 4-5 Switching of Doublet Precursor RTPM to Quartet Precursor RTPM / p85 (0096.jp2)
- References / p97 (0108.jp2)
- Chapter V Relation of RTPM and Radical-Excited Molecule Interactions / p99 (0110.jp2)
- References / p103 (0114.jp2)
- Chapter VI Application of RTPM / p104 (0115.jp2)
- 6-1 RTPM in Conventional Photochemical System / p104 (0115.jp2)
- 6-2 Trial Application of RTPM for the Excited States Quenching Processes / p110 (0121.jp2)
- References / p121 (0132.jp2)
- Acknowledgements / p122 (0133.jp2)