Stereocomplex formation between enantiomeric poly(lactic acid)s ポリ乳酸のステレオコンプレックス形成

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著者

    • 辻, 秀人, 1961- ツジ, ヒデト

書誌事項

タイトル

Stereocomplex formation between enantiomeric poly(lactic acid)s

タイトル別名

ポリ乳酸のステレオコンプレックス形成

著者名

辻, 秀人, 1961-

著者別名

ツジ, ヒデト

学位授与大学

京都大学

取得学位

工学博士

学位授与番号

甲第5183号

学位授与年月日

1992-07-23

注記・抄録

博士論文

目次

  1. 論文目録 / (0001.jp2)
  2. CONTENTS / p1 (0004.jp2)
  3. GENERAL INTRODUCTION / p1 (0007.jp2)
  4. CHAPTER 1 STEREOCOMPLEX FORMATION IN CONCENTRATED SOLUTION / p21 (0017.jp2)
  5. INTRODUCTION / p21 (0017.jp2)
  6. EXPERIMENTAL / p23 (0018.jp2)
  7. 1.Materials / p23 (0018.jp2)
  8. 2.Viscosity Measurement / p24 (0019.jp2)
  9. 3.¹H NMR Spectroscopy / p25 (0019.jp2)
  10. 4.Differential Scanning Calorimetry / p25 (0019.jp2)
  11. RESULTS AND DISCUSSION / p26 (0020.jp2)
  12. 1.Viscosity Measurement / p26 (0020.jp2)
  13. 2.Phase Diagram / p31 (0022.jp2)
  14. 3.Polymer Radius in Solution / p36 (0025.jp2)
  15. 4.¹H NMR Study / p38 (0026.jp2)
  16. 5.DSC Study / p42 (0028.jp2)
  17. CONCLUSION / p44 (0029.jp2)
  18. REFERENCES / p46 (0030.jp2)
  19. CHAPTER 2 CALORIMETRIC STUDIES ON BLEND FILMS CAST FROM DILUTE SOLUTION / p49 (0031.jp2)
  20. INTRODUCTION / p49 (0031.jp2)
  21. EXPERIMENTAL / p51 (0032.jp2)
  22. 1.Materials / p51 (0032.jp2)
  23. 2.Differential Scanning Calorimetry / p53 (0033.jp2)
  24. RESULTS / p53 (0033.jp2)
  25. 1.Effect of Molecular Weight / p53 (0033.jp2)
  26. 3.Effect of Mixing Ratio of Isomers / p60 (0037.jp2)
  27. 4.Effect of Solvent / p64 (0039.jp2)
  28. DISCUSSION / p67 (0040.jp2)
  29. CONCLUSION / p73 (0043.jp2)
  30. REFERENCES / p74 (0044.jp2)
  31. CHAPTER 3 DIFFERENTIAL SCANNING CALORIMETRIC STUDIES ON COMPLEX BLENDS PRECIPITATED FROM MIXED SOLUTIONS / p76 (0045.jp2)
  32. INTRODUCTION / p76 (0045.jp2)
  33. EXPERIMENTAL / p77 (0045.jp2)
  34. 1.Materials / p77 (0045.jp2)
  35. 2.Differential Scanning Calorimetry / p79 (0046.jp2)
  36. RESULTS / p79 (0046.jp2)
  37. 1.Effect of Stirring Rate / p79 (0046.jp2)
  38. 2.Effect of Mixing Ratio of Isomers / p81 (0047.jp2)
  39. 3.Effect of Molecular weight / p87 (0050.jp2)
  40. 4.Effect of Solvent / p92 (0053.jp2)
  41. 5.Effect of Solution Concentration / p94 (0054.jp2)
  42. DISCUSSION / p96 (0055.jp2)
  43. CONCLUSION / p100 (0057.jp2)
  44. REFERENCES / p102 (0058.jp2)
  45. CHAPTER 4 MORPHOLOGICAL STUDY ON STEREOCOMPLEX FORMED IN ACETONITRILE SOLUTION / p104 (0059.jp2)
  46. INTRODUCTION / p104 (0059.jp2)
  47. EXPERIMENTAL / p106 (0060.jp2)
  48. 1.Materials / p106 (0060.jp2)
  49. 2.Electron Microscopic Observation / p107 (0060.jp2)
  50. RESULTS / p107 (0060.jp2)
  51. 1.Effect of Molecular Weight / p109 (0061.jp2)
  52. 2.Effect of Mixing Ratio of Isomers / p111 (0062.jp2)
  53. 3.Effect of Solution Concentration / p111 (0062.jp2)
  54. 4.Effect of Crystallization Temperature / p115 (0064.jp2)
  55. DISCUSSION / p115 (0064.jp2)
  56. REFERENCES / p121 (0067.jp2)
  57. CHAPTER 5 CALORIMETRIC STUDIES ON STEREOCOMPLEX FORMED IN ACETONITRILE SOLUTION / p123 (0068.jp2)
  58. INTRODUCTION / p123 (0068.jp2)
  59. EXPERIMENTAL / p124 (0069.jp2)
  60. 1.Materials / p124 (0069.jp2)
  61. 2.Differential Scanning Calorimetry / p127 (0070.jp2)
  62. 3.Optical Rotation Measurement / p127 (0070.jp2)
  63. RESULTS / p128 (0071.jp2)
  64. 1.Yield of Precipitates / p128 (0071.jp2)
  65. 2.Effects of Different Factors on Complexation / p133 (0073.jp2)
  66. DISCUSSION / p139 (0076.jp2)
  67. REFERENCES / p146 (0080.jp2)
  68. CHAPTER 6 PHASE STRUCTURE OF THE STEREOCOMPLEX CRYSTALLIZED FROM A DILUTE ACETONITRILE SOLUTION AS STUDIED BY HIGH RESOLUTION SOLID STATE ¹³C NMR SPECTROSCOPY / p148 (0081.jp2)
  69. INTRODUCTION / p148 (0081.jp2)
  70. EXPERIMENTAL / p149 (0081.jp2)
  71. 1.Materials / p149 (0081.jp2)
  72. 2.¹³C NMR Measurement / p151 (0082.jp2)
  73. 3.Differential Scanning Calorimetry / p152 (0083.jp2)
  74. RESULTS AND DISCUSSION / p152 (0083.jp2)
  75. 1.DSC Study / p152 (0083.jp2)
  76. 2.¹³C NMR Study / p154 (0084.jp2)
  77. CONCLUSION / p167 (0090.jp2)
  78. REFERENCES / p169 (0091.jp2)
  79. CHAPTER 7 PHASE DIAGRAM OF BINARY BLENDS FROM COPOLYMERS / p171 (0092.jp2)
  80. INTRODUCTION / p171 (0092.jp2)
  81. EXPERIMENTAL / p172 (0093.jp2)
  82. 1.Materials / p172 (0093.jp2)
  83. 2.Differential Scanning Calorimetry / p173 (0093.jp2)
  84. RESULTS / p174 (0094.jp2)
  85. 1.Blending the Same Polymer / p176 (0095.jp2)
  86. 2.Blending between D-rich PLA and L-rich PLA with Similar Optical Purity / p180 (0097.jp2)
  87. 3.Blending between D-Polymer and PLAs / p184 (0099.jp2)
  88. 4.Blending between 1:1 DL Copolymer and PLAs / p190 (0102.jp2)
  89. DISCUSSION / p194 (0104.jp2)
  90. REFERENCES / p198 (0106.jp2)
  91. SUMMARY / p199 (0106.jp2)
  92. LIST OF PUBLICATIONS / p204 (0109.jp2)
  93. ACKNOWLEDGEMENTS / p206 (0110.jp2)
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各種コード

  • NII論文ID(NAID)
    500000089213
  • NII著者ID(NRID)
    • 8000000986026
  • DOI(NDL)
  • NDL書誌ID
    • 000000253527
  • データ提供元
    • NDL-OPAC
    • NDLデジタルコレクション
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