Stereocomplex formation between enantiomeric poly(lactic acid)s ポリ乳酸のステレオコンプレックス形成

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著者

    • 辻, 秀人, 1961- ツジ, ヒデト

書誌事項

タイトル

Stereocomplex formation between enantiomeric poly(lactic acid)s

タイトル別名

ポリ乳酸のステレオコンプレックス形成

著者名

辻, 秀人, 1961-

著者別名

ツジ, ヒデト

学位授与大学

京都大学

取得学位

工学博士

学位授与番号

甲第5183号

学位授与年月日

1992-07-23

注記・抄録

博士論文

目次

  1. 論文目録 (1コマ目)
  2. CONTENTS/p1 (4コマ目)
  3. GENERAL INTRODUCTION/p1 (7コマ目)
  4. CHAPTER 1 STEREOCOMPLEX FORMATION IN CONCENTRATED SOLUTION/p21 (17コマ目)
  5. INTRODUCTION/p21 (17コマ目)
  6. EXPERIMENTAL/p23 (18コマ目)
  7. 1.Materials/p23 (18コマ目)
  8. 2.Viscosity Measurement/p24 (19コマ目)
  9. 3.¹H NMR Spectroscopy/p25 (19コマ目)
  10. 4.Differential Scanning Calorimetry/p25 (19コマ目)
  11. RESULTS AND DISCUSSION/p26 (20コマ目)
  12. 1.Viscosity Measurement/p26 (20コマ目)
  13. 2.Phase Diagram/p31 (22コマ目)
  14. 3.Polymer Radius in Solution/p36 (25コマ目)
  15. 4.¹H NMR Study/p38 (26コマ目)
  16. 5.DSC Study/p42 (28コマ目)
  17. CONCLUSION/p44 (29コマ目)
  18. REFERENCES/p46 (30コマ目)
  19. CHAPTER 2 CALORIMETRIC STUDIES ON BLEND FILMS CAST FROM DILUTE SOLUTION/p49 (31コマ目)
  20. INTRODUCTION/p49 (31コマ目)
  21. EXPERIMENTAL/p51 (32コマ目)
  22. 1.Materials/p51 (32コマ目)
  23. 2.Differential Scanning Calorimetry/p53 (33コマ目)
  24. RESULTS/p53 (33コマ目)
  25. 1.Effect of Molecular Weight/p53 (33コマ目)
  26. 3.Effect of Mixing Ratio of Isomers/p60 (37コマ目)
  27. 4.Effect of Solvent/p64 (39コマ目)
  28. DISCUSSION/p67 (40コマ目)
  29. CONCLUSION/p73 (43コマ目)
  30. REFERENCES/p74 (44コマ目)
  31. CHAPTER 3 DIFFERENTIAL SCANNING CALORIMETRIC STUDIES ON COMPLEX BLENDS PRECIPITATED FROM MIXED SOLUTIONS/p76 (45コマ目)
  32. INTRODUCTION/p76 (45コマ目)
  33. EXPERIMENTAL/p77 (45コマ目)
  34. 1.Materials/p77 (45コマ目)
  35. 2.Differential Scanning Calorimetry/p79 (46コマ目)
  36. RESULTS/p79 (46コマ目)
  37. 1.Effect of Stirring Rate/p79 (46コマ目)
  38. 2.Effect of Mixing Ratio of Isomers/p81 (47コマ目)
  39. 3.Effect of Molecular weight/p87 (50コマ目)
  40. 4.Effect of Solvent/p92 (53コマ目)
  41. 5.Effect of Solution Concentration/p94 (54コマ目)
  42. DISCUSSION/p96 (55コマ目)
  43. CONCLUSION/p100 (57コマ目)
  44. REFERENCES/p102 (58コマ目)
  45. CHAPTER 4 MORPHOLOGICAL STUDY ON STEREOCOMPLEX FORMED IN ACETONITRILE SOLUTION/p104 (59コマ目)
  46. INTRODUCTION/p104 (59コマ目)
  47. EXPERIMENTAL/p106 (60コマ目)
  48. 1.Materials/p106 (60コマ目)
  49. 2.Electron Microscopic Observation/p107 (60コマ目)
  50. RESULTS/p107 (60コマ目)
  51. 1.Effect of Molecular Weight/p109 (61コマ目)
  52. 2.Effect of Mixing Ratio of Isomers/p111 (62コマ目)
  53. 3.Effect of Solution Concentration/p111 (62コマ目)
  54. 4.Effect of Crystallization Temperature/p115 (64コマ目)
  55. DISCUSSION/p115 (64コマ目)
  56. REFERENCES/p121 (67コマ目)
  57. CHAPTER 5 CALORIMETRIC STUDIES ON STEREOCOMPLEX FORMED IN ACETONITRILE SOLUTION/p123 (68コマ目)
  58. INTRODUCTION/p123 (68コマ目)
  59. EXPERIMENTAL/p124 (69コマ目)
  60. 1.Materials/p124 (69コマ目)
  61. 2.Differential Scanning Calorimetry/p127 (70コマ目)
  62. 3.Optical Rotation Measurement/p127 (70コマ目)
  63. RESULTS/p128 (71コマ目)
  64. 1.Yield of Precipitates/p128 (71コマ目)
  65. 2.Effects of Different Factors on Complexation/p133 (73コマ目)
  66. DISCUSSION/p139 (76コマ目)
  67. REFERENCES/p146 (80コマ目)
  68. CHAPTER 6 PHASE STRUCTURE OF THE STEREOCOMPLEX CRYSTALLIZED FROM A DILUTE ACETONITRILE SOLUTION AS STUDIED BY HIGH RESOLUTION SOLID STATE ¹³C NMR SPECTROSCOPY/p148 (81コマ目)
  69. INTRODUCTION/p148 (81コマ目)
  70. EXPERIMENTAL/p149 (81コマ目)
  71. 1.Materials/p149 (81コマ目)
  72. 2.¹³C NMR Measurement/p151 (82コマ目)
  73. 3.Differential Scanning Calorimetry/p152 (83コマ目)
  74. RESULTS AND DISCUSSION/p152 (83コマ目)
  75. 1.DSC Study/p152 (83コマ目)
  76. 2.¹³C NMR Study/p154 (84コマ目)
  77. CONCLUSION/p167 (90コマ目)
  78. REFERENCES/p169 (91コマ目)
  79. CHAPTER 7 PHASE DIAGRAM OF BINARY BLENDS FROM COPOLYMERS/p171 (92コマ目)
  80. INTRODUCTION/p171 (92コマ目)
  81. EXPERIMENTAL/p172 (93コマ目)
  82. 1.Materials/p172 (93コマ目)
  83. 2.Differential Scanning Calorimetry/p173 (93コマ目)
  84. RESULTS/p174 (94コマ目)
  85. 1.Blending the Same Polymer/p176 (95コマ目)
  86. 2.Blending between D-rich PLA and L-rich PLA with Similar Optical Purity/p180 (97コマ目)
  87. 3.Blending between D-Polymer and PLAs/p184 (99コマ目)
  88. 4.Blending between 1:1 DL Copolymer and PLAs/p190 (102コマ目)
  89. DISCUSSION/p194 (104コマ目)
  90. REFERENCES/p198 (106コマ目)
  91. SUMMARY/p199 (106コマ目)
  92. LIST OF PUBLICATIONS/p204 (109コマ目)
  93. ACKNOWLEDGEMENTS/p206 (110コマ目)
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各種コード

  • NII論文ID(NAID)
    500000089213
  • NII著者ID(NRID)
    • 8000000986026
  • DOI(NDL)
  • NDL書誌ID
    • 000000253527
  • データ提供元
    • NDL ONLINE
    • NDLデジタルコレクション

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