Studies on functionalization of complex molecules with low valent transition metal complexes 低原子価遷移金属錯体を用いる複雑分子の官能基変換に関する研究
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著者
書誌事項
- タイトル
-
Studies on functionalization of complex molecules with low valent transition metal complexes
- タイトル別名
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低原子価遷移金属錯体を用いる複雑分子の官能基変換に関する研究
- 著者名
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川淵, 浩之
- 著者別名
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カワフチ, ヒロユキ
- 学位授与大学
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岡山大学
- 取得学位
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博士 (工学)
- 学位授与番号
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乙第2567号
- 学位授与年月日
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1993-03-28
注記・抄録
博士論文
目次
- CONTENTS / (0003.jp2)
- Chapter1.Introduction and General Summary / p1 (0004.jp2)
- Chapter2.Vanadium(II)-Promoted Cyclization of 5,6-Enals or 5,6-Ynals / p19 (0013.jp2)
- 2-1.A Stereoselective Approach to trans-2-Alkyl-or 2-Alkylidenecyclopentanols / p22 (0015.jp2)
- 2-2.Scope and Limitation of the Cyclization Reaction / p26 (0017.jp2)
- 2-3.Mechanistic Assumption / p27 (0017.jp2)
- 2-4.Experimental Section / p29 (0018.jp2)
- Chapter3.Deoxygenation of Epoxides and Acyloins with a Vanadium(II)-THF Complex / p37 (0022.jp2)
- 3-1.Conversion of Epoxides to Olefins / p41 (0024.jp2)
- 3-2.Conversion of Epoxides to Halohydrins / p45 (0026.jp2)
- 3-3.Removal of α-Hydroxyl Group of Acyloins / p47 (0027.jp2)
- 3-4.Mechanistic Assumption / p50 (0029.jp2)
- 3-5.Experimental Section / p52 (0030.jp2)
- Chapter4.Cyanoalkylations of Aldehydes Using Electrogenerated Base as a Catalyst / p65 (0036.jp2)
- 4-1.An Improved Cyanoalkylation Method of Aldehydes / p68 (0038.jp2)
- 4-2.Mechanistic Assumption / p76 (0042.jp2)
- 4-3.Experimental Section / p78 (0043.jp2)
- Chapter5.Cobaloxime-Assisted Electroreductive 1,2-Acyl Migration of 2-Alkyl-2-(bromomethyl)alkanones / p87 (0047.jp2)
- 5-1.Ring Enlargement of 2-Alkyl-2-(bromomethyl)-alkanones via 1,2-Acyl Migration / p90 (0049.jp2)
- 5-2.Mechanistic Assumption / p97 (0052.jp2)
- 5-3.Experimental Section / p100 (0054.jp2)
- Chapter6.Radical Cyclization of Bromo Acetals by Use of Cobaloxime and Sacrificial Electrodes / p111 (0059.jp2)
- 6-1.Radical Cyclization by Using Cobaloxime and Sacrificial Anode / p115 (0061.jp2)
- 6-2.Mechanistic Assumption / p119 (0063.jp2)
- 6-3.Experimental Section / p120 (0064.jp2)
- Publication List / p125 (0066.jp2)
- Acknowledgement / p129 (0068.jp2)